Abstract
The isomerization of 2,3-dimethylbut-1-ene and the decomposition of 2-methyl-3-butyn-2-ol were carried out over a number of solid base catalysts. Rubidium amide supported on alumina was the most active for the isomerization, which proceeds almost to the equilibrium in 10 min at 201 K. The isomerization is a very useful test reaction for determining the relative activities of very strong solid bases. However, weak solid bases such as K+-exchanged Y zeolite are totally inactive for the isomerization. The decomposition of 2-methyl-3-butyn-2-ol is a suitable reaction to discriminate acidic and basic catalysts. It can be also used for estimating the basic property of weak bases such as lithium hydroxide supported on alumina. However, caution is necessary for strongly basic catalysts because of strong adsorption of the products, acetylene and acetone.
Similar content being viewed by others
References
T. Baba, H. Handa and Y. Ono, J. Chem. Soc. Faraday Trans. 90 (1994) 187.
Y. Ono and T. Baba, Catal. Today 38 (1997) 321.
H. Handa, T. Baba, H. Yamada, T. Takahashi and Y. Ono, Catal. Lett. 44 (1997) 119.
T. Baba, A. Kato, H. Handa and Y. Ono, Catal. Lett. 47 (1997) 77.
T. Baba, H. Handa and Y. Ono, Catal. Lett. 50 (1998) 83.
T. Baba, A. Kato, H. Takahashi, F. Toriyama, H. Handa, Y. Ono and H. Sugisawa, J. Catal. 176 (1998) 488.
T. Ando, Stud. Surf. Sci. Catal. 90 (1994), and references therein.
J.H. Clerk, D.E. Cork and M.S. Robertson, Chem. Lett. (1983) 1145.
D.E. Bergbreider and J.J. Lalonde, J. Org. Chem. 52 (1957) 1601.
H. Tsuji, H. Kabashima, H. Kita and H. Hattori, Reac. Kinet. Catal. Lett. 56 (1995) 363.
H. Handa, T. Baba, H. Sugisawa and Y. Ono, J. Mol. Catal., in press.
T. Yamaguchi, J.-H. Zhu, Y. Wang, M. Komatu and M. Ookawa, Chem. Lett. (1997) 989.
Y. Fu, T. Baba and Y. Ono, Appl. Catal. A 166 (1998) 425.
Y. Fu, T. Baba and Y. Ono, Appl. Catal. A 176 (1999) 203.
Y. Fu, T. Baba and Y. Ono, Appl. Catal. A 178 (1999) 219.
J. Take, N. Kikuchi and Y. Yoneda, J. Catal. 21 (1974) 164.
K. Tanabe, M. Misono, Y. Ono and H. Hattori, New Solid Acids and Bases, Stud. Surf. Sci. Catal., Vol. 51 (Kodansha/Elsevier, Tokyo/Amsterdam, 1989) p. 26.
H. Lauron-Pernot, F. Luck and J.M. Popa, Appl. Catal. 78 (1991) 213.
M. Huang and S. Kaliaguine, Catal. Lett. 18 (1993) 373.
T. Baba, R. Koide and Y. Ono, J. Chem. Soc. Chem. Commun. (1991) 691.
T. Baba, G.-J. Kim and Y. Ono, J. Chem. Soc. Faraday Trans. 88 (1992) 891.
T. Baba, S. Hikita, R. Koide, T. Hanada, T. Tanaka and Y. Ono, J. Chem. Soc. Faraday Trans. 89 (1993) 3177.
T. Baba, S. Hikita, T. Hanada, T. Tanaka, S. Yoshida and Y. Ono, J. Mol. Catal. A 98 (1995) 49.
T. Baba, S. Hikita, H. Handa and Y. Ono, Res. Chem. Intermed. 24 (1998) 495.
W.T. Reiche, J. Catal. 94 (1985) 547.
J.J. Lemserton, M. Trouzeydio and M. Guisnet, Appl. Catal. 54 (1989) 91.
T. Nakatsuka, H. Kawasaki, S. Yamashita and S. Kohjiya, Bull. Chem. Soc. Jpn. 52 (1979) 2449.
E. Suzuki and Y. Ono, Bull. Chem. Soc. Jpn. 61 (1988) 1008.
A. Corma, V. Formes, R.M. Martin-Aranda and E. Rey, J. Catal. 134 (1992) 58.
A. Corma and R.M. Martin-Aranda, Appl. Catal. A 105 (1993) 271.
Y. Ono, Stud. Surf. Sci. Catal. 5 (1980) 19.
K. Hatada, Y. Takeyama and Y. Ono, Bull. Chem. Soc. Jpn. 51 (1976) 448.
Z.-H. Fu and Y. Ono, J. Catal. 145 (1994) 166.
A. Corma, V. Fornes, R.M. Martin-Aranda, H. Garcia and J. Primo, Appl. Catal. 39 (1990) 237.
F. Yagi, N. Kanuka, H. Tsuji, S. Nakata, H. Kita and H. Hattori, Micropor. Mater. 9 (1997) 229.
F. Yagi, H. Tsuji and H. Hattori, Micropor. Mater. 9 (1997) 237.
F. Yagi and H. Hattori, Micropor. Mater. 9 (1997) 247.
P.E. Hathaway and M.E. Davis, J. Catal. 116 (1989) 263, 279.
P.E. Hathaway and M.E. Davis, J. Catal. 119 (1989) 497.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Handa, H., Fu, Y., Baba, T. et al. Characterization of strong solid bases by test reactions. Catalysis Letters 59, 195–200 (1999). https://doi.org/10.1023/A:1019093126342
Issue Date:
DOI: https://doi.org/10.1023/A:1019093126342