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On the mechanism of CO adsorption on a silica‐supported ruthenium catalyst

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Abstract

The adsorption of CO at room temperature on a Ru/SiO2 catalyst has been studied by means of FTIR spectroscopy. Spectral evidence for formation of water molecules and a quantity of very dispersed ruthenium on the catalyst surface during CO adsorption was found. On the basis of these experimental results a new reaction scheme for the interaction of CO with a silica‐supported ruthenium catalyst is proposed.

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Authors and Affiliations

  1. Department of Chemistry, Bilkent University, 06533, Bilkent, Ankara, Turkey

    Margarita Kantcheva & Safak Sayan

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  1. Margarita Kantcheva
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  2. Safak Sayan
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Correspondence to Margarita Kantcheva.

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Kantcheva, M., Sayan, S. On the mechanism of CO adsorption on a silica‐supported ruthenium catalyst. Catalysis Letters 60, 27–38 (1999). https://doi.org/10.1023/A:1019082218590

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