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Novel synthesis of diethyl carbonate over palladium/MCM‐41 catalysts

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Abstract

The catalytic activities of palladium supported on Si‐MCM‐41 and Ti‐MCM‐41 catalysts have been studied in the reactions of CO + C2H5ONO. It reveals that copper and titanium used as additives are able to increase the yields of DEC and DEO. The additive copper is favorable to DEO formation, while the additive titanium is favorable to DEC formation.

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Authors and Affiliations

  1. The Chemistry Department, ZheJiang University, HangZhou, 310037, PR China

    Jiang Xuan Zhen & Su Yue Hua

  2. Academic Sinica, Institute of Chemistry, Taipei, Taiwan, ROC

    Chien Shu Hua

Authors
  1. Jiang Xuan Zhen
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  2. Su Yue Hua
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  3. Chien Shu Hua
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Zhen, J.X., Hua, S.Y. & Hua, C.S. Novel synthesis of diethyl carbonate over palladium/MCM‐41 catalysts. Catalysis Letters 69, 153–156 (2000). https://doi.org/10.1023/A:1019082209214

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  • DOI: https://doi.org/10.1023/A:1019082209214

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