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Molecular hydrogen-originated protonic acid site as active site on solid acid catalyst

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Abstract

The protonic acid sites are formed from hydrogen molecules on Pt/SO4 2--ZrO2 , and the resulting protonic acid sites act as active sites for acid-catalyzed reactions. Promotion of molecular hydrogen on the activities is observed not only for the Pt/SO4 2--ZrO2, but also for the other catalysts such as a physical mixture of Pt/SiO2 and H-ZSM5, and Co.Mo/SiO2-/Al2O3 . A molecular hydrogen-originated protonic acid site is proposed as a widely applicable concept for an active site on solid acid catalysts.

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Authors
  1. Hideshi Hattori
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  2. Tetsuya Shishido
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Hattori, H., Shishido, T. Molecular hydrogen-originated protonic acid site as active site on solid acid catalyst. Catalysis Surveys from Asia 1, 205–213 (1997). https://doi.org/10.1023/A:1019081031021

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