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TPD study about the surface modification of some Ni/spinel catalysts in the hydrodechlorination of 1,2,4‐trichlorobenzene. Influence on hydrogenation ability

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Abstract

NiAl2O4 supports and fresh and reactivated Ni/NiAl2O4 catalysts were tested in the gas phase hydrodechlorination of 1,2,4‐trichlorobenzene. Fresh catalysts hydrogenate 1,2,4‐trichlorobenzene to cyclohexane in the first 30 min of reaction at 523 K. An irreversible partial chlorination of the catalytic surface makes the hydrogenation of the aromatic ring difficult.

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Authors and Affiliations

  1. Facultat de Química, Universitat Rovira i Virgili, Pl. Imperial Tarraco, 1, 43005, Tarragona, Spain

    Y. Cesteros & P. Salagre

  2. Escola Tècnica Superior d'Enginyeria, Universitat Rovira i Virgili, Pl. Imperial Tarraco, 1, 43005, Tarragona, Spain

    F. Medina & J.E. Sueiras

Authors
  1. Y. Cesteros
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  2. P. Salagre
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  3. F. Medina
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  4. J.E. Sueiras
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Cesteros, Y., Salagre, P., Medina, F. et al. TPD study about the surface modification of some Ni/spinel catalysts in the hydrodechlorination of 1,2,4‐trichlorobenzene. Influence on hydrogenation ability. Catalysis Letters 67, 147–153 (2000). https://doi.org/10.1023/A:1019057219750

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