Abstract
Atom-planting, a useful method to prepare some metallosilicates having zeolitic structure, was proposed. By treatment of highly siliceous zeolite with metal chloride vapor at selected temperature, metal cation could be introduced into the defect sites (hydroxyl nests) of zeolite framework. By the atom-planting method, some metallosilicates which are difficult to be synthesized by hydrothermal synthesis could be prepared. The vapor phase shape-selective alkylation of ethylbenzene with ethanol, and the liquid phase selective oxidation with hydrogen peroxide on the metallosilicates prepared by atom-planting method were reviewed.
Similar content being viewed by others
References
H.K. Beyer and I. Belenykakja, Stud. Surf. Sci. Catal. 5 (1980) 203.
S. Namba, A. Inaka and T. Yashima, Chem. Lett. (1984) 817.
G.T. Kerr, ACS Chem. Ser. 121 (1973) 219.
M.W. Anderson, J. Klinowski and L. Xinsheng, J. Chem. Soc. Chem. Commun. (1984) 1596.
C.D. Chang, C.T.-W. Chu, J.N. Miale, R.F. Bridger and R.B. Calvert, J. Am. Chem. Soc. 106 (1984) 8143.
R.M. Dessau and G.T. Kerr, Zeolites 4 (1984) 315.
S. Namba, K. Yamagishi and T. Yashima, Chem. Lett. (1987) 1109.
P. Wu, T. Komatsu and T. Yashima, J. Phys. Chem. 99 (1995) 10923.
B. Kraushaar and J.H.C. van Hooff, Catal. Lett. 1 (1988) 81.
K. Yamagishi, S. Namba and T. Yashima, Stud. Surf. Sci. Catal. 49 (1989) 459.
K. Yamagishi, S. Namba and T. Yashima, Bull. Chem. Soc. Jpn. 64 (1991) 949.
P. Wu, T. Komatsu, T. Yashima, S. Nakata and H. Shoji, Microporous Materials 12 (1997) 25.
P. Wu, T. Komatsu and T. Yashima, Stud. Surf. Sci. Catal. 90 (1994) 295.
P. Wu, T. Komatsu and T. Yashima, J. Phys. Chem. 100 (1996) 10316.
K. Yamagishi, S. Namba and T. Yashima, J. Phys. Chem. 95 (1991) 872.
G.L. Woolery, L.B. Alemany, R.M. Dessau and A.W. Chester, Zeolites 6 (1986) 14.
A. Endoh, K. Nishimiya, K. Tsutsumi and T. Takaishi, Stud. Surf. Sci. Catal. 46 (1989) 779.
T. Yashima, K. Yamagishi, S. Namba, S. Nakata and A. Asaoka, Stud. Surf. Sci. Catal. 37 (1988) 175.
H.K.C. Timken and E. Oldfield, J. Am. Chem. Soc. 109 (1987) 7669.
C.R. Bayense, A.P.M. Kentger, J.W. de Haan and L.J.M. van de Ven, J. Phys. Chem. 96 (1992) 775.
T. Yashima, K. Yamagishi and S. Namba, Stud. Surf. Sci. Catal. 60 (1991) 171.
G. Perego, G. Bellussi, C. Corno, M. Taramasso, F. Buonomo and A. Esposito, in: Proc. 7th Intern. Zeolite Confer.(Kodansha/Elsevier, Tokyo/Amsterdam, 1986) p. 129.
P. Wu, T. Komatsu and T. Yashima, Stud. Surf. Sci. Catal. 105 (1997) 663.
D.H. Olson and W.O. Haag, in: ACS Symp. Ser., Vol. 248 (ACS, Washington, DC, 1984) p. 275.
T, Yashima, J.-H. Kim, H. Ohta, S. Namba and T. Komatsu, Stud. Surf. Sci. Catal. 90 (1994) 379.
P. Wu, T. Komatsu and T. Yashima, J. Chem. Soc. Faraday Trans. 92 (1996) 861.
W.W. Kaeding, C. Chu, L.B. Young, B. Weinstein and J. Butler, J. Catal. 67 (1981) 159.
T. Yashima, Y. Sakaguchi and S. Namba, Stud. Surf. Sci. Catal. 7 (1981) 739.
J.-H. Kim, S. Namba and T. Yashima, Zeolites 11 (1991) 59.
J.-H. Kim, S. Namba and T. Yashima, J. Jpn. Petrol. Inst. 39 (1996) 79.
J. Wei, J. Catal. 76 (1982) 433.
S. Namba, J.-H. Kim and T. Yashima, Stud. Surf. Sci. Catal. 83 (1994) 279.
D.H. Olson, R.M. Lago and W.O. Haag, J. Catal. 61 (1980) 390.
Y. Sendoda and Y. Ono, Zeolites 8 (1988) 101.
R.M. Lago, W.O. Haag, R.J. Mikovsky, D.H. Olson, S.D. Helling, K.D. Schmitt and G.T. Kerr, in: Proc. 7th Intern. Zeolite Confer.(Kodansha/Elsevier, Tokyo/Amsterdam, 1986) p. 677.
K. Yamagishi, S. Namba and T. Yashima, J. Catal. 121 (1990) 47.
B. Notari, Advances in Catalysis 41 (1996) 253.
M.A. Camblor, A. Corma and J. Perez-Pariente, Zeolites 13 (1993) 82.
G. Sanker, F. Roy, J.M. Thomas, G.N. Greaves, A. Corma, B.R. Dobson and A.J. Dent, J. Chem. Soc. Chem. Commun. (1994) 2279.
P. Wu, T. Komatsu and T. Yashima, Stud. Surf. Sci. Catal. 105 (1997) 663.
P. Wu, T. Komatsu and T. Yashima, J. Catal. 168 (1997) 400.
A. Thangaraj, S. Sivasanker and P. Ratnasamy, J. Catal. 131 (1991) 394.
A. Zecchina, G. Spoto, S. Bordiga, F. Geobaldo, G. Petrini, G. Leofanti, M. Padovan, M. Mantegazza and P. Roffia, Stud. Surf. Sci. Catal. 75 (1993) 719.
A. Thangaiay, R. Kumar, S.P. Mirajkar and P. Ratnasamy, J. Catal. 130 (1990) 1.
J.S. Reddy, S. Sivasanker and P. Ratnasamy, J. Mol. Catal. 69 (1991) 383.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Yashima, T. Preparation of metallosilicates with zeolite structure by atom-planting method. Catalysis Surveys from Asia 2, 121–132 (1998). https://doi.org/10.1023/A:1019034610065
Issue Date:
DOI: https://doi.org/10.1023/A:1019034610065