Abstract
Chemical transformations in supercritical fluids (SCFs) have enormous potential advantages. The possibilities of rate enhancement and adjustable selectivities will motivate the research of molecular catalysis in SCFs. Recent progress in the organometallic catalysis under supercritical conditions is reviewed with emphasis on the benefits of utilization of supercritical carbon dioxide (scCO2) both as a reaction medium and reactant.
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Ikariya, T., Kayaki, Y. Supercritical fluids as reaction media for molecular catalysis. Catalysis Surveys from Asia 4, 39–50 (2000). https://doi.org/10.1023/A:1019032004130
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DOI: https://doi.org/10.1023/A:1019032004130