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Propane and oxygen action on NOx adspecies on low-exchanged Cu-ZSM-5

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Abstract

A surface intermediate with a C/N ratio close to 3 has been shown by TPD to form at co-adsorption of NO and propane as well as NO, propane and O2 on low-exchanged Cu-ZSM-5. The adsorption of NO, propane and oxygen has been studied to evaluate their effect on the formation of this complex. Its formation is accompanied by a decrease in the concentration of surface nitrite–nitrate. The kinetics of nitrite–nitrate adspecies formation as a function of the reagents concentration and temperature has been investigated. Some NO adspecies have been found to decompose yielding N2O.

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References

  1. M. Iwamoto and H. Hamada, Catal. Today 10 (1991) 57.

    Article  CAS  Google Scholar 

  2. J. Haggin, in: C&EN (8 January 1996).

  3. R. Burch and P. Millington, Appl. Catal. B2 (1993) 101.

    Article  Google Scholar 

  4. B. J. Cho, J. Catal. 142 (1993) 418.

    Article  CAS  Google Scholar 

  5. C. J. Bennet, P. S. Bennet, S. E. Golunski, J. W. Hayes and A. P. Walker, Appl. Catal. A86 (1992) L1.

    Google Scholar 

  6. K. A. Bathke, C. Li, M. C. Kung, B. Yang and H. H. Kung, Catal. Lett. 31 (1995) 287.

    Article  Google Scholar 

  7. H. Hamada, Y. Kintaichi, M. Sasaki, T. Ito and M. Tabata, Appl. Catal. 75 (1991) L1.

    Article  CAS  Google Scholar 

  8. C. N. Montreuil and M. Shelef, Appl. Catal. B1 (1992) L1.

    Article  Google Scholar 

  9. B. J. Adelman, T. Beutel, G.-D. Lei and W. M. H. Sachtler, Appl. Catal. B11 (1996) L1.

    Article  Google Scholar 

  10. M. Iwamoto and H. Takeda, Catal. Today 27 (1996) 71.

    Article  CAS  Google Scholar 

  11. F. Witzel, G. A. Sill and W. K. Hall, J. Catal. 149 (1994) 229.

    Article  CAS  Google Scholar 

  12. Y. Li, T. L. Slager and J. N. Armor, J. Catal. 150 (1994) 229.

    Google Scholar 

  13. T. Beutel, B. J. Adelman, G.-D. Lei and W. M. H. Sachtler, Catal. Lett. 32 (1995) 83.

    Article  CAS  Google Scholar 

  14. R. H. H. Smits and Y. Iwasawa, Appl. Catal. B6 (1995) L201.

    Article  Google Scholar 

  15. C. Yokoyama and M. Misono, J. Catal. 150 (1994) 9.

    Article  CAS  Google Scholar 

  16. T. Beutel, B. J. Adelman and W. M. H. Sachtler, Catal. Lett. 37 (1996) 125.

    Article  CAS  Google Scholar 

  17. D. J. Parrilo, J. Catal. 129 (1991) 202.

    Article  Google Scholar 

  18. A. Sepulveda-Escribano, C. Marquez-Alvarez, I. Rodriguez-Ramos, A. Guerrero-Ruiz and J. L. G. Fierro, Catal. Today 17 (1993) 167.

    Article  CAS  Google Scholar 

  19. A. V. Simakov, N. N. Sazonova, E. V. Rebrov, O. V. Komova and G. B. Barannik, in: Proc. Russian-Korean Seminar on Catalysis, Novosibirsk, 16-19 May 1995, p. 139.

  20. V. V. Kharlamov, V. I. Bogomolov, N. V. Mirzabekova and A. V. Pospelov, Zhurnal Physicheskoi Khimii 50 (1976) 343.

    CAS  Google Scholar 

  21. A. V. Simakov, React. Kinet. Catal. Lett. 97 (1996) 331.

    Google Scholar 

  22. S. Larsen, in: Proc. US-Russia Workshop on Environ. Catal., Wilmington, DE, 1994, p. 21.

  23. V. A. Sadykov, G. M. Alikina, R. V. Bunina, S. L. Baron, S. A. Veniaminov, V. N. Romannikov, V. P. Doronin, A. Ya. Rozovskii, V. F. Tretyakov, V. V. Lunin, E. V. Lunina, A. N. Kharlanov and A. V. Matyshak, in: Proc. 1st World Congress Environ. Catal., Pisa, 1-5 May 1995, p. 315.

  24. Y. Li and J. N. Armor, Appl. Catal. 76 (1991) L1.

    Article  CAS  Google Scholar 

  25. Z. Chajar, M. Primet, H. Praliaud, M. Chevrier, C. Gauthier and F. Mathis, Catal. Lett. 28 (1994) 33.

    Article  CAS  Google Scholar 

  26. CRC Handbook of Chemistry and Physics, 73rd Ed. (CRC Press, Boca Raton, FL, 1992/1993) p. 121.

  27. M. Iwamoto and H. Takeda, Catal. Today 27 (1996) 71.

    Article  CAS  Google Scholar 

  28. N. N. Sazonova, O. V. Komova, E. V. Rebrov, A. V. Simakov, N. A. Kulikovskaya, V. A. Rogov, R. V. Olkhov and G. B. Barannik, React. Kinet. Catal. Lett. 60 (1997) 313.

    CAS  Google Scholar 

  29. Z. Schay and L. Guczi, Catal. Today 17 (1993) 175.

    Article  CAS  Google Scholar 

  30. M. Iwamoto, H. Yahiro, K. Tanda, N. Mizuno, Y. Mine and S. Kagawa, J. Phys. Chem. 95 (1991) 3727.

    Article  CAS  Google Scholar 

  31. M. Sasaki, H. Hamada, Y. Kintaichi and T. Ito, Catal. Lett. 15 (1992) 297.

    Article  CAS  Google Scholar 

  32. Y. Ukisu, S. Sato, A. Abe and K. Yoshida, Appl. Catal. B2 (1993) 147.

    Article  Google Scholar 

  33. K. A. Bethke, C. Li, M. C. Kung, B. Yang and H. H. Kung, Catal. Lett. 31 (1995) 287.

    Article  CAS  Google Scholar 

  34. T. Beutel, J. Sarkany, G.-D. Lei, J. Y. Yan and W. M. H. Sachtler, J. Phys. Chem. 100 (1996) 845.

    Article  CAS  Google Scholar 

  35. G. D. Lei, B. J. Adelman, J. Sarkany and W. M. H. Sachtler, Appl. Catal. B5 (1995) 245.

    Article  Google Scholar 

  36. J. Valyon and W. K. Hall, J. Phys. Chem. 97 (1993) 1204.

    Article  CAS  Google Scholar 

  37. Z. Wang, A. V. Sklyarov and G. W. Keulks, Catal. Today 33 (1997) 291.

    Article  CAS  Google Scholar 

  38. J. Valyon and W. K. Hall, J. Catal. 143 (1993) 520.

    Article  CAS  Google Scholar 

  39. G. Spoto, S. Bordiga, D. Scarano and A. Zecchina, Catal. Lett. 13 (1992) 39.

    Article  CAS  Google Scholar 

  40. Y. Li and W. K. Hall, J. Catal. 129 (1991) 202.

    Article  CAS  Google Scholar 

  41. A. V. Kucherov, G. L. Gerlock, H.-W. Jen and M. Shelef, Catal. Today 27 (1996) 79.

    Article  CAS  Google Scholar 

  42. J. Leglise, J. O. Petunchi and W. K. Hall, J. Catal. 86 (1984) 392.

    Article  CAS  Google Scholar 

  43. Y. Li and J. N. Armor, Appl. Catal. B1 (1992) L21.

    Article  Google Scholar 

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Authors and Affiliations

  1. Novosibirsk State University, Novosibirsk, 630090, Russia

    E.V. Rebrov

  2. Federal Scientific Center “Boreskov, Institute of Catalysis”, Novosibirsk, 630090, Russia

    A.V. Simakov, N.N. Sazonova, V.A. Rogov & G.B. Barannik

Authors
  1. E.V. Rebrov
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  2. A.V. Simakov
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  3. N.N. Sazonova
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  4. V.A. Rogov
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  5. G.B. Barannik
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Rebrov, E., Simakov, A., Sazonova, N. et al. Propane and oxygen action on NOx adspecies on low-exchanged Cu-ZSM-5. Catalysis Letters 51, 27–40 (1998). https://doi.org/10.1023/A:1019024715245

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