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The catalysis of the Ruff oxidative degradation of aldonic acids by titanium‐containing zeolites

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Abstract

Ti‐BEA and Ti‐FAU, obtained by post‐synthesis treatment, and TS‐1, obtained by direct hydrothermal synthesis, have been tested as catalysts for the Ruff oxidative degradation of calcium d‐gluconate to d‐arabinose using diluted hydrogen peroxide as oxidant. Only large‐pore zeolites Ti‐BEA and Ti‐FAU were found to be active. It was shown, in particular, that a very rapid leaching of titanium occurred and that the titanium species present in the solution were responsible for the catalytic activity observed.

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Authors
  1. Gwénaëlle Hourdin
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  2. Alain Germain
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  3. Claude Moreau
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  4. François Fajula
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Hourdin, G., Germain, A., Moreau, C. et al. The catalysis of the Ruff oxidative degradation of aldonic acids by titanium‐containing zeolites. Catalysis Letters 69, 241–244 (2000). https://doi.org/10.1023/A:1019022023326

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