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Supported binary oxide monolayers as selective oxidation catalysts: Bi2Mo3O12/TiO2

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Abstract

Monolayers of bismuth molybdates supported on low-area TiO2 (anatase) catalyse the oxidation/isomerisation of 1-butene to butadiene and 2-butenes with combined selectivities of 80–100% and show significantly lower specific rates of deep oxidation than does \(\alpha\)-Bi2Mo3O12. As loadings are increased above 2 wt% (equivalent to one monolayer), selectivities remain high and, although the butadiene yields are generally only moderate, in some cases they exceed that shown by the unsupported \(\alpha\)-phase.

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Authors and Affiliations

  1. Chemistry Unit, Institute for Physical and Environmental Sciences, Brunel University, Uxbridge, UB8 3PH, UK

    Ashish Bhakoo, Geoffrey C. Bond, Robert D. Rees, Björn Sauerhammer, Adrian O. Taylor & Ian York

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  1. Ashish Bhakoo
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  2. Geoffrey C. Bond
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  3. Robert D. Rees
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  4. Björn Sauerhammer
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  6. Ian York
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Bhakoo, A., Bond, G.C., Rees, R.D. et al. Supported binary oxide monolayers as selective oxidation catalysts: Bi2Mo3O12/TiO2 . Catalysis Letters 57, 55–60 (1999). https://doi.org/10.1023/A:1019018825975

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