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Photooxidation of cyclohexene and benzene with oxygen by fullerenes grafted on mesoporous FSM-16

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Abstract

Fullerenes (C60 and C70) are grafted on mesoporous FSM-16 (pore size 2.7 nm), and the grafted fullerenes showed high activities (TON up to 3070 in 9 h) for allylic oxidation of cyclohexene with oxygen in benzene under the irradiation of UV-vis light. In these reactions, phenol is also formed by the oxidation of benzene with cyclohexene hydroperoxide produced in the allylic oxidation of cyclohexene.

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Authors and Affiliations

  1. Catalysis Research Center, Hokkaido University, Sapporo, 060-0811, Japan

    Atsushi Fukuoka, Keiko Fujishima, Midori Chiba & Masaru Ichikawa

  2. Division of Biological Sciences, Graduate School of Science, Hokkaido University, Sapporo, 060-0810, Japan

    Akihiko Yamagishi

  3. Toyota Central R&D Labs., Inc., Aichi, 480–1192, Japan

    Shinji Inagaki & Yoshiaki Fukushima

Authors
  1. Atsushi Fukuoka
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  2. Keiko Fujishima
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  3. Midori Chiba
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  4. Akihiko Yamagishi
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  5. Shinji Inagaki
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  6. Yoshiaki Fukushima
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  7. Masaru Ichikawa
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Fukuoka, A., Fujishima, K., Chiba, M. et al. Photooxidation of cyclohexene and benzene with oxygen by fullerenes grafted on mesoporous FSM-16. Catalysis Letters 68, 241–244 (2000). https://doi.org/10.1023/A:1019008225627

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  • DOI: https://doi.org/10.1023/A:1019008225627

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