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The Influence of Yttrium Implantation on the Oxidation of Impure Iron Containing C and Mn at 700°C

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Abstract

A study of impurity-yttrium interactions hasbeen performed during iron oxidation [p(O2)= 0.04 Pa, T = 700°C]. Yttrium-implanted specimensalways exhibit better oxidation behavior compared withblank specimens. On pure iron or the Fe 0.054 wt.%C alloy thebeneficial effect is attributed toFe2YO4 formation. With themanganese-containing alloys (Fe 0.2 wt.%Mn), theprotective effect of yttrium is attributed to YMnO3 formation. The best oxidationbehavior is obtained with implanted Fe0.18 wt.%Mn-0.041wt.%C alloys due to the formation of an YMnO3oxide subscale at the scale-alloy interface. Yttriumimplantation also hinders carbon segregation at theoxide-alloy interface. This effect ensures better scaleadherence. With the most-impure alloy, yttriumimplantation also changes the growth process fromexternal cation diffusion to predominant inward-oxygendiffusion.

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Authors
  1. H. Buscail
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  2. C. Courty
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  3. M. F. Stroosnijder
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  4. Y. P. Jacob
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  5. J. P. Larpin
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Buscail, H., Courty, C., Stroosnijder, M.F. et al. The Influence of Yttrium Implantation on the Oxidation of Impure Iron Containing C and Mn at 700°C. Oxidation of Metals 49, 561–581 (1998). https://doi.org/10.1023/A:1018842727206

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