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Conversion process of chlorine containing polysilanes into silicon carbide: Part I Synthesis and crosslinking of poly(chloromethyl)silanes–carbosilanes and their transformation into inorganic amorphous silicon carbide

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Abstract

Synthesis of chlorine containing polysilanes by catalytic redistribution is described and the obtained polymers are characterized by infrared (IR)-, magic angle spinning nuclear magnetic resonance (MAS-NMR)-spectroscopy and elemental analysis. The pyrolysis of such polysilanes was investigated by thermoanalysis, IR-, MAS NMR- and electron spin resonance (ESR)-spectroscopy. The conversion process from polysilane into polycarbosilane is described in terms of the results of the performed investigations and a model of the process is developed. Differences between this conversion process and those for chlorine free polysilanes or polycarbosilanes previously described by other authors are discussed.

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Authors and Affiliations

  1. Institutes of Ceramic Materials, 09596, Freiberg, Germany

    H.-P MARTIN & E MULLER

  2. Institutes of Inorganic Chemistry, 09596, Freiberg, Germany

    R RICHTER & G ROEWER

  3. Institutes of Analytical Chemistry, Freiberg University of Mining and Technology, 09596, Freiberg, Germany

    E BRENDLER

Authors
  1. H.-P MARTIN
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  2. E MULLER
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  3. R RICHTER
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  4. G ROEWER
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  5. E BRENDLER
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MARTIN, HP., MULLER, E., RICHTER, R. et al. Conversion process of chlorine containing polysilanes into silicon carbide: Part I Synthesis and crosslinking of poly(chloromethyl)silanes–carbosilanes and their transformation into inorganic amorphous silicon carbide. Journal of Materials Science 32, 1381–1387 (1997). https://doi.org/10.1023/A:1018577111536

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