Abstract
The binuclear hydroxo complexes [{M(C6F5)2(μOH)}2]2−(M=PdandPt)reactwithN-substituted salicylaldimines (HSal=NR) or β-ketoimines (RN=CMeCH2COR′) to give the corresponding N-substituted salicylaldiminato or β-ketoiminato mononuclear complexes, [M(C6F5)2(Sal=NR)]− (M=Pd or Pt; R= Me, Et, Ph, o-MeC6H4, p-MeC6H4 or p-ClC6H4) or [(C6F5)2M{N(R)C(CH3)CHC(O)R′}]− (M=Pd or Pt; R=o-MeC6H4 or p-MeC6H4; R′=Me or Ph), respectively. The complexes have been characterized by partial elemental analyses, conductance measurements and spectroscopic (i.r. and 1H and 19F- n.m.r.) methods.
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Ruiz, J., Rodri´guez, V., Vicente, C. et al. Reactivity of hydroxo palladium and platinum complexes towards N-substituted salicylaldimines and β-ketoimines. Transition Metal Chemistry 22, 502–506 (1997). https://doi.org/10.1023/A:1018571531737
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DOI: https://doi.org/10.1023/A:1018571531737