Abstract
The kinetics of aquation of cis- and trans-[Co(en)2NO2Cl]+ have been investigated in aqueous mixtures of 2-methoxyethanol, 2-ethoxyethanol, isopropoxyethanol, 2-butoxyethanol, 1,2-dimethoxyethane, ethylene glycol and n-propanol over a range of temperatures. The results are discussed in terms of the hydrophobic effect in these systems.
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Grancčicčova´, O. Effect of cosolvent hydrophobicity on the aquation of cis- and trans-chloro(nitro)bis(ethylenediamine)cobalt(III) ions. Transition Metal Chemistry 22, 471–474 (1997). https://doi.org/10.1023/A:1018507212172
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DOI: https://doi.org/10.1023/A:1018507212172