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Synthesis, characterisation and crystal structure analysis of bis (pyridine-2-carbaldehyde thiosemicarbazonato) cobalt(III) thio-cyanate monohydrate

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Abstract

The crystal structure of [CoL2](SCN)·H2O (L = pyridine-2-carbaldehyde thiosemicarbazonato) is reported. The structure, along with other physico-chemical studies, establishes that the compound is a low spin CoIII complex. This resolves confusion arising out of an e

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References

  1. F. A. French, E. J. Blanz, S. C. Shaddix and R. W. Brockman, J. Med. Chem., 17, 172 (1974).

    Article  CAS  PubMed  Google Scholar 

  2. A.B. Ablov and N. I. Belichuk, Russ. J. Inorg. Chem., 14, 93 (1969).

    Google Scholar 

  3. D. X. West, P. K. Ahrweiler, C. Ertem, J. P. Scovill, D. L. Klayman, J. L. Flippen Aderson, R. Giradi, C. George and L. K. Powell, Transition Met. Chem., 10, 264 (1985).

    Article  CAS  Google Scholar 

  4. H. Beraldo and L. Tosi, Inorg. Chim. Acta, 75, 249 (1983).

    Article  CAS  Google Scholar 

  5. R. Raina and T. S. Srivastava, Inorg. Chim. Acta, 67, 83 (1982).

    Article  CAS  Google Scholar 

  6. J. P. Scovill, D. L. Klayman and, C. F. Franchino, J. Med. Chem., 25, 1261 (1982).

    Article  CAS  PubMed  Google Scholar 

  7. A. G. Bingham, H. Bogge, A. Muller, E. W. Ainscough and A. M. Brodie, J. Chem. Soc., Dalton Trans, 493 (1987).

  8. M. Mohan, M. Kumar, A. Kumar, P. H. Madhurnath and N. K. Jha, J. Inorg. Biochem., 32, 239 (1988).

    Article  CAS  PubMed  Google Scholar 

  9. A. Maiti, A. K. Guha and S. Ghosh, J. Inorg. Biochem., 33, 57 (1988).

    Article  CAS  PubMed  Google Scholar 

  10. S. K. Chattopadhyay and S. Ghosh, Inorg. Chim. Acta, 163, 245 (1989).

    Article  CAS  Google Scholar 

  11. S. K. Chattopadhyay and S. Ghosh, Inorg. Chim. Acta, 131, 15 (1987).

    Article  CAS  Google Scholar 

  12. S. K. Chattopadhyay, M. Hossain, S. Ghosh and A. K. Guha, Transition Met. Chem., 15, 473 (1990).

    Article  CAS  Google Scholar 

  13. T. T. Bamgboye and O. A. Bamgboye, Inorg. Chim. Acta, 105, 223 (1985).

    Article  CAS  Google Scholar 

  14. S. K. Chattopadhyay, T. C. W. Mak, B. S. Luo, L. K. Thompson, A. Rana and S. Ghosh, Polyhedron, 14, 3661 (1995).

    Article  CAS  Google Scholar 

  15. G. M. Sheldrick, SHELX86, Program for Solution of Crystal Structures, University of Gö ttingen, Germany (1986).

    Google Scholar 

  16. G. M. Sheldrick, SHELX76, Program for Crystal Structure Determination, University of Cambridge, England, (1976).

    Google Scholar 

  17. W. J. Geary, Coord. Chem. Rev., 7, 81 (1971).

    Article  CAS  Google Scholar 

  18. A. Sabatini and I. Bertini, Inorg. Chem., 4, 957 (1965).

    Google Scholar 

  19. V. N. Biyushkin, V. I. Gerasimov, N. I. Belichuk, V. N. Kaftant, M. A. Simonov and N. V. Belov, Sov. Phys. Crystallogr., 24, 28 (1979).

    Google Scholar 

  20. V. I. Gerasimov, V. N. Biyushkin, N. I. Belichuk and N. V. Belov, Sov. Phys. Crystallogr., 24, 33 (1979).

    Google Scholar 

  21. T. Uechi and T. Oniki, Bull. Chem. Soc. Jpn, 55, 971 (1982).

    Article  CAS  Google Scholar 

  22. A. K. Nandi, W. S. Sheldrick and S. Ghosh, Acta Crystallogr. C, 42, 1570 (1986).

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, BE College (Deemed University), Howrah, 711103, India

    Shyamal K. Chattopadhyay

  2. Department of Physics, University of Calcutta, 92 APC Road, Calcutta, 700009, India

    Tapati Banerjee & Priyabrata Roychoudhury

  3. Department of Chemistry, The Chinese University of Hong Kong, Hong Kong

    Thomas C.W. Mak

  4. Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Calcutta, 700032, India

    Saktiprosad Ghosh

Authors
  1. Shyamal K. Chattopadhyay
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  2. Tapati Banerjee
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  3. Priyabrata Roychoudhury
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  4. Thomas C.W. Mak
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  5. Saktiprosad Ghosh
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Chattopadhyay, S.K., Banerjee, T., Roychoudhury, P. et al. Synthesis, characterisation and crystal structure analysis of bis (pyridine-2-carbaldehyde thiosemicarbazonato) cobalt(III) thio-cyanate monohydrate. Transition Metal Chemistry 22, 216–219 (1997). https://doi.org/10.1023/A:1018448004478

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  • DOI: https://doi.org/10.1023/A:1018448004478

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