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Electrochemical behaviour of ferrocenyl-containing acyl thiourea derivatives

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Abstract

Twenty four N-ferrocenoyl-N′-aryl(alkyl or ferrocenyl) thiourea derivatives were prepared and ten of them investigated by cyclic voltammetric method in DMF or CH2Cl2 solutions. The compounds exhibit a higher redox potential than ferrocene. Although distant from the redox centre, the substituents on N′ can influence the redox potential of ferrocenyl via intramolecular hydrogen bonding.

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References

  1. J. Cernak, J. Chomic, P. Ktschy, D. Surcinova and M. Dzurilla, Inorg. Chim. Acta, 191, 85 (1991).

    Article  Google Scholar 

  2. A. Mohamadou, I. Dechamps-Olivier and J-P. Barbier, Polyhedron, 13, 1363 (1994).

    Article  CAS  Google Scholar 

  3. M. M. Khalil, A. H. H. Elghandour and M. Mostafa, Polyhedron, 13, 3295 (1994).

    Article  CAS  Google Scholar 

  4. Ji-tao Wang, Yun-wen Zhang, Yu-ming Xu, Yao-feng Yuan and Shenghua Gao, Chem. J. Chin. Univ., 14, 801 (1993).

    CAS  Google Scholar 

  5. Ji-tao Wang, Yu-ming Xu, Yao-feng Yuan, Bin Wang, Yong-an Yang and Su-ming Ye, Chem. J. Chin. Univ., 16, 1415 (1995).

    CAS  Google Scholar 

  6. H. L. Hans. and H. Hart, J. Org. Chem., 24, 280 (1959).

    Article  Google Scholar 

  7. R. H. Khan, Agric. Biol. Chem. 40, 1881 (1976).

    CAS  Google Scholar 

  8. Ji-tao Wang, Yao-feng Yuan, Yu-ming Xu and Yun-wen Zhang, Acta Chim. Sinica 53, 32 (1996).

    Google Scholar 

  9. Ji-tao Wang, Yao-feng Yuan, Yu-ming Xu, Yun-wen Zhang, Ru-ji Wang and Hong-gen Wang, J Organometal. Chem., 481, 211 (1994).

    Article  CAS  Google Scholar 

  10. A. J. Bard and L. R. Faulkner, Electrochemical Methods, Wiley, New York 1980, p. 256.

    Google Scholar 

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Yuan, YF., Zhang, LY., Cheng, JP. et al. Electrochemical behaviour of ferrocenyl-containing acyl thiourea derivatives. Transition Metal Chemistry 22, 281–283 (1997). https://doi.org/10.1023/A:1018424826768

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