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Nineteen-membered pentaazamacrocyclic complexes bearing tetraamide groups

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Abstract

A new series of CoII, NiII, CuII and ZnII complexes incorporating pentaazamacrocyclic ligands has been prepared via the template condensation of o-aminobenzoic acid with succinic or phthalic acids in the presence of diethylenetriamine. The overall geometry and mode of bonding have been deduced on the basis of elemental analyses, i.r., 1H-n.m.r., e.p.r. and u.v.-vis. spectral studies, and conductivity and magnetic susceptibility measurements. An octahedral geometry is proposed for all the complexes, where five coordination sites are occupied by the macrocyclic nitrogens and the sixth by an anion.

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Authors and Affiliations

  1. Department of Chemistry, Islamic University of Gaza (PNA), Egypt

    Omar S. M. Nasman

  2. Department of Chemistry, Al-Azhar University, Gaza (PNA)

    Rajai M. Baraka, Adnan A. Khaldi & Issa El Nahhal

  3. Department of Chemistry, Aligarh Muslim University, Aligarh, 202002, India

    Saji P. Varkey & Mohammad Shakir

Authors
  1. Omar S. M. Nasman
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  2. Rajai M. Baraka
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  3. Adnan A. Khaldi
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  4. Issa El Nahhal
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  5. Saji P. Varkey
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  6. Mohammad Shakir
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Nasman, O.S.M., Baraka, R.M., Khaldi, A.A. et al. Nineteen-membered pentaazamacrocyclic complexes bearing tetraamide groups. Transition Metal Chemistry 22, 273–276 (1997). https://doi.org/10.1023/A:1018420725860

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