Abstract
A nonhomogeneous magnetic field is generated electrochemically in an electrodeposition cell which is also an interferometer. Magnetic field strength near 0.5T produce a detectable by interferometry convective slow rotation in a diamagnetic electrolyte with electroactive (Cu2+) and indifferent (Mn2+) paramagnetic ions present in an otherwise stagnant solution with the cathode over the anode (C/A). Approximate calculation of forces and flows are attempted.
Similar content being viewed by others
References
R. N. O'Brien and K. S. V. Santhanam. J. Electrochem. Soc. 129 (1982) 1266.
Idem, Electrochim. Acta 23 (1987) 1679.
Idem, J. Appl. Electrochem. 20 (1990) 427.
Idem, ibid. 20 (1990) 781.
Idem, in Interfinish of 84, Metal Finishing International Conference Proceedings.
Idem, Can. J. Chem. 65 (1987) 2009.
C. Forgacs, J. Liebovitz, R. N. O'Brien and K. S. Spiegler, Electrochim. Acta 20 (1975) 555.
Z. H. Gu and T. Z. Fahidy, J. Electrochem. Soc. 134 (1987) 2241.
T. Z. Fahidy, J. Appl. Electrochem. 13 (1983) 555.
Z. H. Gu, J. Chen and T. Z. Fahidy, ibid. 140 (1993) 408.
R. N. O'Brien and H. Kolny, Can. J. Chem. 56 (1978) 591.
O. D. Jafimenko, `Electricity and Magnetism', Appleton-Century-Crofts, New York (1966) pp. 486–96.
`Handbook of Chemistry and Physics', 70th edn, Chemical Rubber Publishing Co., Boca Raton, FA (1989/90).
L. N. Muloy, `Magnetic Susceptibility', Interscience, New York (1963) p. 1846.
P. M. Selwood, `Magnetic Susceptibility', in Techniques of Organic Chemistry', vol. 1, Physical Methods, part IV (edited by A. Weissberger), Interscience, New York (1960) p. 2877.
R. N. O'Brien and H. Kolny, Corrosion 34 (1978) 262.
R. N. O'Brien, J. Chem. & Eng. Data 13 (1968) 2.
`Handbook of Chemistry and Physics', 60th edn., Chemical Rubber Publishing Co., Boca Raton, FA (1958/59).
D. J. Rose and M. Clarke, Jr., in `Plasmas and Controlled Fusion', MIT Press, Cambridge, MA (1961) pp. 103–7.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
O'BRIEN , R.N., SANTHANAM , K.S.V. Magnetic field assisted convection in an electrolyte of nonuniform magnetic susceptibility. Journal of Applied Electrochemistry 27, 573–578 (1997). https://doi.org/10.1023/A:1018402813235
Issue Date:
DOI: https://doi.org/10.1023/A:1018402813235