Abstract
The NaF–WO3 , NaCl–Na3WO3F3 , and NaCl–NaWO3F systems were studied by thermal analysis and x-ray diffraction. Solid-state transformations were revealed, and the primary crystallization ranges were outlined. The refractive indices of the sodium fluorotungstates were measured. The thermodynamic functions of Na3WO3F3were derived from emf measurements.
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REFERENCES
Balikhin, V.S., Pavlovskii, V.A., and Reznichenko, V.A., Electrorefining of Tungsten Waste in Salt Melts, Tsvetn. Met. (Moscow), 1974, no. 10, pp. 59–62.
Balikhin, V.S. and Pavlovskii, V.A., Tungsten Electroplating in Salt Melts, Tsvetn. Met. (Moscow), 1975, no. 3, pp. 70–75.
Pavlovskii, V.A. and Reznichenko, V.A., Electrolytes for Tungsten Refining in Melts, Izv. Akad. Nauk SSSR, Met., 1982, no. 2, pp. 26–30.
Schitz-Dumont, O. and Bruns, J., Die Systeme Alkalifluorid/Wolfram(VI)-Oxyd, Z. Anorg. Allg. Chem., 1953, vol. 271, pp. 347–351.
Minenkov, V.I., Petrov, S.M., and Ivanova, N.S., Application of Reversible Oxygen Electrodes in Oxygen-Containing Melts, Izv. Vyssh. Uchebn. Zaved., Chern. Metall., 1960, no. 7, pp. 10–15.
Kolotyi, A.A. and Delimarskii, Yu.K., Electrode Function of Platinum in Melts, Ukr. Khim. Zh. (Russ. Ed.), 1962, vol. 28, pp. 537–541.
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Pavlovskii, V.A., Reznichenko, V.A. Phase Relations in the NaF–WO3 , NaCl–Na3WO3F3 , and NaCl–NaWO3F Systems. Inorganic Materials 37, 846–848 (2001). https://doi.org/10.1023/A:1017951818875
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DOI: https://doi.org/10.1023/A:1017951818875