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Reactions of ortho-Phenylenediamine with a Nickel Trimethylacetate Complex

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Abstract

Interaction of ortho-phenylenediamine with the nonanuclear nickel trimethylacetate cluster Ni9(μ4-OH)3(μ3-OH)3(μ n -OOCMe3)12(HOOCCMe3)4(I) in an amine deficiency yields the antiferromagnetic trinuclear complex [Ni3{μ-N,N"-(NH2)2C6H4}2(HCCOOCMe3)3(μ3-OH)(μ-OOCCMe3)4]+(OOCCMe3)–(III) containing bridging diamine ligands. Reaction of excess diamine with Ior IIIleads to the formation of the paramagnetic monomer Ni{η2-o-(NH2)2C6H4}2(OOCCMe3)2(IV), which reacts with atmospheric oxygen to form the known bis(semiquinonediimine) complex Ni[1,2-(NH)2C6H4]2(V).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russia

    A. E. Malkov, G. G. Aleksandrov, V. N. Ikorskii, A. A. Sidorov, I. G. Fomina, S. E. Nefedov, V. M. Novotortsev, I. L. Eremenko & I. I. Moiseev

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  1. A. E. Malkov
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  2. G. G. Aleksandrov
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  3. V. N. Ikorskii
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  4. A. A. Sidorov
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  5. I. G. Fomina
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  6. S. E. Nefedov
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  7. V. M. Novotortsev
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  8. I. L. Eremenko
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  9. I. I. Moiseev
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Malkov, A.E., Aleksandrov, G.G., Ikorskii, V.N. et al. Reactions of ortho-Phenylenediamine with a Nickel Trimethylacetate Complex. Russian Journal of Coordination Chemistry 27, 636–643 (2001). https://doi.org/10.1023/A:1017949505373

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