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Compounds of Undecahydrodecaborate Anion B10H11–

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Abstract

Conditions for the synthesis of salts of the B10H11 –anion with different cations in the Cat2B10H10+ RCOOH (R = H, CF3; Cat = Me4N+, Et4N+, Bu4N+, Ph4P+, Ph4As+) systems were studied depending on the acid strength (pK a) and size of the cation. It was established that reactions with trifluoroacetic acid give compounds of this anion with any one of the quaternary ammonium, phosphonium, or arsonium cations, while formic acid can only give salts with the largest of these cations.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russia

    V. N. Mustyatsa, N. A. Votinova, L. V. Goeva, K. Yu. Zhizhin, E. A. Malinina & N. T. Kuznetsov

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  1. V. N. Mustyatsa
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  2. N. A. Votinova
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  3. L. V. Goeva
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  4. K. Yu. Zhizhin
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  5. E. A. Malinina
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  6. N. T. Kuznetsov
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Mustyatsa, V.N., Votinova, N.A., Goeva, L.V. et al. Compounds of Undecahydrodecaborate Anion B10H11–. Russian Journal of Coordination Chemistry 27, 622–624 (2001). https://doi.org/10.1023/A:1017941303556

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