Skip to main content
Log in

Effects of Ca addition on the microstructure and mechanical properties of AZ91magnesium alloy

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The effects of Ca addition on the microstructure and mechanical properties of AZ91 magnesium alloy have been studied. The results show that the Ca addition can refine the microstructure, reduce the quantity of Mg17Al12 phase, and form new Al2Ca phase in AZ91 magnesium alloy. With the Ca addition, the tensile strength and elongation of AZ91magnesium alloy at ambient temperature are reduced, whereas Ca addition confers elevated temperature strengthening on AZ91 magnesium alloy. The tensile strength at 150°C increases with increasing Ca content. The impact toughness of AZ91magnesium alloy increases, and then declines as the Ca content increases. The tensile and impact fractographs exhibit intergranular fracture features, Ca addition changes the pattern and quantity of tearing ridge, with radial or parallel tearing ridge increasing, tensile strength, elongation and impact toughness reduce.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. E. Brown, International Magnesium Association 55th Annual World Conference, Light Metal Age, 1998 Vol. 56(7–8) pp. 86–93.

    Google Scholar 

  2. M. O. Pekguleryuz and M. M. Avedesian, J. Japan Inst. Light Metals 42(12) (1992) 679.

    Google Scholar 

  3. E. J. Lavernia, E. Gomez and N. J. Grant, Mater. Sci. Eng. 95 (1987) 225.

    Google Scholar 

  4. A. Luo and M. O. Pekguleryuz, J. Mater. Sci. 29 (1994) 5259.

    Google Scholar 

  5. R. Ninomiya, T. Ojiro and K. Kubota, Acta Metall. Mater. 43(2) (1995) 669.

    Google Scholar 

  6. S. Lee, S. H. Lee and D. H. Kim, Effect of Y, Sr, and Nd Additions on the Microstructure and Microstructure Mechanism of Squeeze-Cast AZ91-X Magnesium Alloys, Metall. and Mater. Trans. 29A(2) (1998) 1221.

    Google Scholar 

  7. I. J. Polmear, Recent Developments in Light Alloys, Mater. Trans., JIM 37(1) (1996) 12.

    Google Scholar 

  8. Y. Carbonneau, A. Couture and A. V. Neste, On the Observation of a New Ternary MgSiCa Phase in Mg-Si Alloys, Metall. Mater. Trans. 29A(6) (1998) 1759.

    Google Scholar 

  9. M. Gilbert, Japanese Patent, 69623 (1924).

  10. R. A. V. Huddle, J. Laing, A. C. Jessup and E. F. Emley, UK Patent, 776649 (1953)

  11. S. Akiyama, Flame-Resistant Magnesium Alloys by Calcium, J. Jpn. Foundry Eng. Soc. 68(1) (1994) 38.

    Google Scholar 

  12. M. Sakamoto, S. Akiyama, T. Hagio and K. Ogi, Control of Oxidation Surface Film and Suppression of Ignition of Molten Mg-Ca Alloy by Ca Addition, ibid. 69(3) (1997) 227.

    Google Scholar 

  13. S. Y. Chang, H. Tezuka and A. Kamio, Mechanical properties and structure of ignition-proof Mg-Ca-Zr alloys produced by squeeze casting, Mater. Trans., JIM 38(6) (1997) 526.

    Google Scholar 

  14. M. Sakamoto and S. Akiyama, Suppression of Ignition and burning of molten Mg alloys by Ca bearing stable oxide film, J. Mater. Sci. Lett. 16(9) (1997) 1048.

    Google Scholar 

  15. A. Luo, Tensile and creep properties of automotive magnesium alloys, JOM 49(11) (1997) 7.

    Google Scholar 

  16. C. Shaw and H. Jones, Structure and mechanical properties of twoMg-Al-Ca alloys consolidated from atomised powder, Mater. Sci. Technol. 15(1) (1999) 78.

    Google Scholar 

  17. Yizhen Lu, Qudong Wang, Xiaoqin Zeng and Wenjiang Ding, Effects of rare earths on the microstructure, properties and fracture behavior of Mg-Al alloys, Mater. Sci. Eng. A 278 (2000) 66.

    Google Scholar 

  18. R. Ferro, A. Saccone and G. Borzone, Rare Earth Metals in Light Alloys, J. Rare Rarths 15(1) (1997) 45.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Qudong, W., Wenzhou, C., Xiaoqin, Z. et al. Effects of Ca addition on the microstructure and mechanical properties of AZ91magnesium alloy. Journal of Materials Science 36, 3035–3040 (2001). https://doi.org/10.1023/A:1017927109291

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1017927109291

Keywords

Navigation