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Degradation of Some Pesticides in Aqueous Solutions by Electron Beam and Gamma-Radiation

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Abstract

Decomposition by ionizing radiations of two pesticides (Lannate and Fenvalerate) present in an aqueous solution has been studied on laboratory-scale experiments. The effect of pH of the solution, the concentration of the pesticide and the irradiation dose on the degradation process was investigated. Gamma-irradiation was carried out in air and in combination with nitrogen, oxygen and ozone. Lannate showed more degradation than Fenvalerate in all conditions investigated. Radiation was not enough to achieve the complete decomposition of the pesticides. Adsorption of the pollutants after irradiation was achieved using granular activated carbon (GAC) and two anion exchangers (Dowex 1-X8 and Lewatit AP 246).

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References

  1. T. H. Y. Tebbutt, Principles of Water Quality Control, Pergamon Press, New York, 1982.

    Google Scholar 

  2. D. C. J. Hinge, Instr. Water Engrs. Sci., 34 (1980) 546.

    Google Scholar 

  3. J. Dojlido,G. A. Best, Chemistry of Water and Water Pollution, Ellis Horwood, New York, 1992.

    Google Scholar 

  4. W. Stevens, Pesticides in the Environment, Marcel Dekker, New York, 1983.

    Google Scholar 

  5. K. Buchel, Chemistry of Pesticides, John Wiley, New York, 1983.

    Google Scholar 

  6. W. C. Hay, Proc. Symp. Radiation for a Clean Environment, Munich, International Atomic Energy Agency (IAEA), 1975, p. 433.

    Google Scholar 

  7. C. Cappadona,P. Guarine,E. Caldero, Proc. Symp. Radiation for a Clean Environment, Munich, IAEA, 1975, p. 265.

    Google Scholar 

  8. D. M. P. Rohrer, Proc. Symp. Radiation for a Clean Environment, Munich, IAEA, 1975, p. 241.

    Google Scholar 

  9. A. M. Dessouki,S. E. Abdel-Aal, Proc. IAEA Intern. Symp. SM, 350, Zakopane, Poland, 1997, p. 221.

    Google Scholar 

  10. A. M. Dessouki,S. E. Abdel-Aal,S. A. Ismail, Arab J. Nucl. Sci. Appl., (1998) 32.

  11. N. Suzuki,M. Teijro,S. Akihisa,H. Hashimoto,W. Kawakami, Intern. J. Appl. Radiation Isotopes, 29 (1978) 103.

    Google Scholar 

  12. M. Washino, Radiat. Phys. Chem., 18 (1981) 83.

    Google Scholar 

  13. N. Piccinini,F. Ferrero, Proc. IAEA Symp., Munich, 1975, p. 249.

  14. A. J. Swallow, Radiation Chemistry, John Wiley, New York, 1973.

    Google Scholar 

  15. B. M. Tolbert,M. H. Krinks, Rad. Res., 2 (1960) 586.

    Google Scholar 

  16. N. Suzuki,T. Nagai,H. Hotta,M. Washino, Intern. J. Appl. Radiation Isotopes, 26 (1975) 726.

    Google Scholar 

  17. N. Suzuki,T. Nagai,H. Hotta,M. Washino, Bull. Chem. Soc. Japan, 48 (1979) 2158.

    Google Scholar 

  18. N. Suzuki,T. Nagai,H. Hotta,M. Washino, Bull. Chem. Soc. Japan, 50 (1977) 1441.

    Google Scholar 

  19. K. Shimada,N. Suzuki,N. Itatani,H. Hotta, Bull. Chem. Soc. Japan, 37 (1964) 1143.

    Google Scholar 

  20. N. Suzuki,T. Miyato,A. Sakumoto,S. Hashimoto,W. Kawa Kami, Intern. J. Appl. Radiation Isotopes, 29 (1978) 103.

    Google Scholar 

  21. J. H. Baxendale,J. A. Wilson, Trans. Faraday Soc., 53 (1957) 344.

    Google Scholar 

  22. N. A. Bach, Rad. Res., 1 (1959) 190.

    Google Scholar 

  23. J. Hoinge, Aspects of Hydrocarbon Radiolysis, Academic Press, New York, 1968.

    Google Scholar 

  24. P. S. Lang,W. K. Ching,D. M. Willber,M. R. Hoffman, Environ. Sci. Technol., 32 (1998) 3142.

    Google Scholar 

  25. M. H. O. Sampa,C. L. Duarte,P. R. Rela,E. S. R. Somessari,C. G. Silveira,A. L. Azevedo, Radiat. Phys. Chem., 52 (1998) 365.

    Google Scholar 

  26. H. Sontheimer,H. Gulde, J. Water Waste Water, 133 (1992) 239.

    Google Scholar 

  27. V. Noll,V. Coumaris,W. S. Hou, Adsorption Technology for Air and Water Pollution Control, Lewis Publishers Inc, New York, 1992.

    Google Scholar 

  28. H. Malissa, Egyptian J. Anal. Chem., 1 (1990) 49.

    Google Scholar 

  29. F. Hamoda,M. S. Al-Awadi, The Second Middle East Conference on Wastewater Management, Cairo, Egypt, 1995, p. 19.

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Abdel Aal, S., Dessouki, A. & Sokker, H. Degradation of Some Pesticides in Aqueous Solutions by Electron Beam and Gamma-Radiation. Journal of Radioanalytical and Nuclear Chemistry 250, 329–334 (2001). https://doi.org/10.1023/A:1017912132599

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