Abstract
Composite materials prepared from barium boromolybdate glasses (MoO3content of 8, 12, or 16 wt %) and a cermet containing iron silicides were characterized by x-ray diffraction and resistivity measurements as a function of temperature. Increasing the content of the semicrystalline constituent first reduces the resistivity and then increases it to its original level. The minimum resistivity of the materials corresponds to a positive temperature coefficient of resistance. The results are interpreted in terms of the micro- and electric structures of the composites.
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REFERENCES
Kharitonov, E.V., Dielektricheskie materialy s neodnorodnoi strukturoi (Inhomogeneous-Structure Dielectric Materials), Moscow: Radio i Svyaz', 1983.
Hill, R., Electrical Transport in Thick Film Resistors, Electrocomp. Sci. Technol., 1980, vol. 6, no. 9, pp. 141–145.
Sachkov, I.N. and Povzner, A.A., Semiconductor-Metal Transition and Transport Behavior of FeSi-FeSi2 Mixed-Phase Systems, Fiz. Tverd. Tela (S.-Peterburg), 1996, vol. 38, no. 10, pp. 2969–2972.
Saifullin, R.S., Neorganicheskie kompozitsionnye materialy (Inorganic Composite Materials), Moscow: Khimiya, 1983.
Kachurina, E.E., Myakinenkov, V.I., and Shcheglova, V.V., Refractory Silicides in Semiconductor Technology, Part 2, Obz. Elektron. Tekh., Ser. 2: Poluprovodn Prib., 1982, no. 7 (903).
Vecherskii, S.I. and Sidorenko, F.A., Electrical Conductivity of Si-Doped Barium Boromolybdate Glass, Neorg. Mater., 1992, vol. 28, no. 7, pp. 1461–1465.
Gel'd, P.V. and Sidorenko, F.A., Silitsidy perekhodnykh metallov chetvertogo perioda (First-Row Transition-Metal Silicides), Moscow: Metallurgiya, 1971.
Rogers, D.B., Shannon, R.D., Sleight, A.W., and Gillson, J.L., Crystal Chemistry of Metal Dioxides with Rutile-Related Structures, Inorg. Chem., 1969, vol. 8, no. 4, pp. 841–849.
Vecherskii, S.I. and Sidorenko, F.A., Electrical Resistivity of FeSi2-MoO3-Glass Composites, Poroshk. Metall. (Kiev), 1991, no. 9, pp. 43–47.
Ambegaokar, V., Halperin, B., and Langer, J., Hopping Conductivity in Disordered Systems, Phys. Rev. B: Solid State, 1971, vol. 4, no. 8, pp. 2612–2620.
Rao, C.N.R. and Gopalakrishnan, J., New Directions in Solid State Chemistry: Structure, Synthesis, Properties, Reactivity, and Materials Design, Cambridge: Cambridge Univ. Press, 1986.
Samsonov, G.V., Dvorina, L.A., and Rud', B.M., Silitsidy (Silicides), Moscow: Metallurgiya, 1979.
Pike, G.E. and Seager, C.H., Electrical Properties and Conduction Mechanisms of Ru-Based Thick-Film (Cermet) Resistors, Appl. Phys., 1977, vol. 17, no. 48 (12), pp. 5152–5169.
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Povzner, A.A., Vecherskii, S.I., Sidorenko, F.A. et al. Electrical Resistivity of Iron Silicide–Barium Boromolybdate Glass Composites. Inorganic Materials 37, 754–757 (2001). https://doi.org/10.1023/A:1017602929487
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DOI: https://doi.org/10.1023/A:1017602929487