Abstract
The influence of several ethoxylated additives (ethyleneglycol and polyethyleneglycol polymers of different molecular weights) on the nucleation, growth mechanism and morphology of zinc electrodeposited from an acidic chloride bath is reported. The electrochemical study was carried out using cyclic voltammetry, inversion potential and chronoamperometric techniques. The dimensionless graphs model was applied to analyse the nucleation process and the results showed that the studied additives have a blocking effect on the electrodeposition of zinc. This effect occurs in the first stages of the nucleation process and is dependent on the molecular weight of the additive. Changes induced by the presence of additives in the morphology and grain size of the deposits were observed using SEM analysis. Results show that the presence of additives modifies the nucleation process and determines the final properties of the deposits.
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References
W.H. Safranek (Ed.), ‘The Properties of Electrodeposited Metals and Alloys’ (AESF, Florida, 1986).
J.W. Dini, ‘Electrodeposition. The Material Science of Coatings and Substrates’ (Noyes Publications, New Jersey, 1995).
D.A. Vermilyea, J. Electrochem. Soc. 106 (1995) 66.
Majid R. Kalantary, Plat. Surf. Finish. 80 (June 1994) 80.
D. Stoychev and S. Rashkov, Commun. Dep. Chem. Bulg. Acad. Sci. 9(4) (1976) 618.
A. Aragón, M.G. Figueroa and R.E. Gana, J. Appl. Electrochem. 22 (1992) 558.
D. Stoychev, I. Vitanova, T. Vitanov and S. Rashkov, Surf. Technol. 7 (1978) 427.
M. Wünsche, R.J. Nichols, R. Schumacher. W. Beckman and H. Meyer, Electrochim. Acta 38 (1993) 647.
M. Pushpavanam and K. Balakrishnam, J. Appl. Electrochem. 26 (1996) 283.
C. Karwas and T. Hepel, J. Electrochem. Soc. 136 (1989) 1672.
R. Fratesi, G. Roventi, G. Giuliani and C.R. Tomachuk, J. Appl. Electrochem. 27 (1997) 1088.
H. Ruiz, G. Trejo, R. Ortega Borges and Y. Meas V., Memorias XIII Congreso de la Sociedad Iberoamericana de Electroquímica (1998) 580.
A. Rojas and I. González, Anal. Chim. Acta 187 (1986) 279.
A. Rojas-Hernández, M.T. Ramírez and I. González, Anal. Chim. Acta 278 (1993) 321.
A. Rojas-Hernández, M.T. Ramírez and I. González, Anal. Chim. Acta 278 (1993) 335.
M. Smith and A.E. Martell, ‘Critical Stability Constants’, Vol. 4 (Plenum Press, New York, 1979).
G. Trejo, R. Ortega Borges, Y. Meas V., E. Chainet, B. Nguyen and P. Ozil, J. Electrochem. Soc. 14 (1998) 4090.
A.J. Bard and L.R. Faulkner, ‘Electrochemical Methods: Fundamental and Applications’ (J. Wiley & Sons, New York, 1980).
G.J. Hills, D.J. Hills, D.J. Schiffrin and J. Thompson, Electrochim. Acta 19 (1974) 657.
S. Fletcher, Electrochim. Acta 28 (1983) 917.
S. Fletcher, C.S. Halliday, D. Gates, M. Westcott, T. Lwin and G. Nelson, J. Electroanal. Chem. 159 (1983) 267.
B.R. Scharifker and G. Hills, Electrochim. Acta 28 (1983) 879.
G. Gunawardena, G. Hills and I. Montenegro, J. Electroanal. Chem. 184 (1985) 371.
G. Gunawardena, G. Hills, I. Montenegro and B. Scharifcker, J. Electroanal. Chem. 138 (1982) 225.
B.R. Scharifker and J. Mostany, J. Electroanal. Chem. 177 (1984) 13.
P.M. Rigano, C. Mayer and T. Chierchie, J. Electroanal. Chem. 248 (1988) 219.
M. Palomar-Pardave, I. González, A.B. Soto and E.M. Arce, J. Electroanal. Chem. 443 (1998) 125.
M. Sánchez Cruz, F. Alonso and J.M. Palacios, J. Appl. Electrochem. 23 (1993) 364.
G. Trejo, A.F. Gil and I. González, J. Electrochem. Soc. 142 (1995) 3404.
G. Barceló, M. Sarret, C. Müller and J. Pregonas, Electrochim. Acta 43 (1998) 13.
H. Yan, J. Downes, P.J. Boden and S.J. Harris, J. Electrochem. Soc. 143 (1996) 1577.
E. Michailova, I. Vitanova, D. Stoychev and A. Mielchev, Electrochim. Acta 38 (1993) 2455.
E. Michailova, I. Vitanova, D. Stoychev and A. Mielchev, J. Electroanal. Chem. 366 (1994) 195.
P.C. Fazio, E.L. Gutman, S.L. Kauffman, J.G. Kramer, C.M. Leinweber, V.A. Mayer, P.A. McGee (Eds), ASTM G5. Standard reference test for making potentiostatic and potentiodynamic anodic polarization measurementes, in ‘Annual Book of ASTM Standards, Vol. 03.02 Wear and Erosion, Metal Corrosion’ (ASTM, Philadelphia, 1993), p. 71.
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Trejo, G., Ruiz, H., Borges, R.O. et al. Influence of polyethoxylated additives on zinc electrodeposition from acidic solutions. Journal of Applied Electrochemistry 31, 685–692 (2001). https://doi.org/10.1023/A:1017580025961
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DOI: https://doi.org/10.1023/A:1017580025961