Abstract
As part of the separation by froth flotation of PVC and PET from waste bottles before recycling, the adsorption mechanism of a lignosulphonate used to selectively render one of the plastics hydrophilic has been studied. As the 'rest' method is not sufficiently sensitive for this purpose, X-ray Photoelectron Spectroscopy analysis was conducted. A method of calculating the surface coverage of both plastics by the reagent is proposed based on the fact that the lignosulphonate contains sulphur whereas PVC and PET do not. The results show that a greater quantity of lignosulphonate adsorbs on PET than PVC, leading to a higher surface coverage of LS on PET. The surface coverage values are a function of the lignosulphonate macromolecular configuration. For the sphere and film configurations hypothetised, the surface coverage values remain less than 1, which is consistent with the patchy adsorption assumed in the calculations.
Similar content being viewed by others
References
C. Le Guern et al., in Proceedings of the XXth International Mineral Processing Congress, Aachen, Germany, September 1997, edited by H. Hoberg and H. von Blottnitz, Vol. 5, p. 319.
K. Saitoh et al., Japan Plastic Age 12 (1975) 25.
N. Fraunholcz et al., in Berg-und Hüttenmännischer Tag, Freiberg, Germany, June 1995, p. 8.
A. Rezanowich and D. A. I. GÖring, Journal of Colloid Science 15 (1960) 452.
R. J. Pugh, International Journal of Mineral Processing 25(1/2) (1989) 101.
J.-M. Plankelee, Ph.D Thesis, University of Paris XIII, France, 1985, p. 105.
V. P. Nedosvitii et al., Refractories 35(5) (1994) 145.
C. Le Guern et al., Minerals Engineering 13(1) (2000) 53.
C. Le Guern, Ph.D. Thesis, Institut National Polytechnique de Lorraine, France, 1997, p. 334.
M.-F. Pinhas, Ph.D. Thesis, Université de Haute Alsace, 1995, p. 163.
M. P. Seah, Surf. Interface Anal. 2 (1980) 222.
J. C. Le Bell, Colloids and Surfaces 9 (1984) 237.
J. C. Ashley, Journal of Electron Spectroscopy and Related Phenomena 46 (1988) 199.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Guern, C.L., Baillif, P., Conil, P. et al. Adsorption of a lignosulphonate polymer onto PVC and PET surfaces: Evaluation by XPS. Journal of Materials Science 36, 1547–1554 (2001). https://doi.org/10.1023/A:1017565201410
Issue Date:
DOI: https://doi.org/10.1023/A:1017565201410