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Novel Stereoselective Synthesis and Molecular and Crystalline Structure of 3-Allyl-4-(4-bromophenyl)-3-cyano-6-oxopiperidine-2-thione

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Abstract

The stereoselective synthesis of 3-allyl-4-(4-bromophenyl)-3-cyano-6-oxopiperidine-2-thione has been carried out by refluxing N-methylmorpholinium 5-[1-(4-bromophenyl)-2-cyano-2-thiocarbamoylethyl]-2,2-dimethyl-1,3-dioxa-6-oxo-4-cyclohexen-4-olate with allyl bromide in ethanol. The structure of the product was confirmed by X-ray investigation.

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Authors and Affiliations

  1. Taras Shevchenko State Pedagogical University, Lugansk, 348011, Ukraine

    S. G. Krivokolysko & V. D. Dyachenko

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 117813

    V. N. Nesterov

  3. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 117913

    V. P. Litvinov

Authors
  1. S. G. Krivokolysko
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  2. V. D. Dyachenko
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  3. V. N. Nesterov
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  4. V. P. Litvinov
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Krivokolysko, S.G., Dyachenko, V.D., Nesterov, V.N. et al. Novel Stereoselective Synthesis and Molecular and Crystalline Structure of 3-Allyl-4-(4-bromophenyl)-3-cyano-6-oxopiperidine-2-thione. Chemistry of Heterocyclic Compounds 37, 315–319 (2001). https://doi.org/10.1023/A:1017555032309

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  • DOI: https://doi.org/10.1023/A:1017555032309

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