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Biophysical applications

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Abstract

Nuclear forward scattering (NFS) of synchrotron radiation was applied to investigate the electronic and magnetic properties of (i) the diamagnetic “picket-fence” porphyrin FeO2(SC6HF4)(TPpivP), which is a model for oxygenated hemoglobin and myoglobin and (ii) the paramagnetic “picket-fence” porphyrin [Fe(CH3COOH)(TPpivP)]—, which is a model for the ferrous state of the prosthetic group, termed P460, of the multi-heme enzyme hydroxylamine oxidoreductase from the bacterium Nitrosomonas europeae.

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Authors and Affiliations

  1. Institut für Physik, Medizinische Universität zu Lübeck, D-23538, Lübeck, Germany

    A.X. Trautwein & H. Winkler

Authors
  1. A.X. Trautwein
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  2. H. Winkler
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Trautwein, A., Winkler, H. Biophysical applications. Hyperfine Interactions 123, 561–570 (1999). https://doi.org/10.1023/A:1017036326459

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  • DOI: https://doi.org/10.1023/A:1017036326459

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