Abstract
Spectral density of random alternating current, which is induced by turbulent pulsations of electrolyte velocity in a cell, is theoretically analyzed within the Ershler–Randles charge transfer model in the Nernst diffusion layer approximation. The effect of electrode potential on the spectral current density is analyzed at various frequencies of hydrodynamic pulsations.
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REFERENCES
Dolin, P.I. and Ershler, B.V., Zh. Fiz. Khim., 1940, vol. 14, p. 886.
Dolin, P.I., Ershler, B.V., and Frumkin, A.N., Zh. Fiz. Khim., 1940, vol. 14, pp. 907, 916.
Dolin, P. and Ershler, B., Acta Physicochim. URSS, 1940, vol. 13, p. 779.
Frumkin, F., Dolin, P., and Ershler, B., Acta Physicochim. URSS, 1940, vol. 13, p. 793.
Randles, J.E.B., Discuss. Faraday Soc., 1947, vol. 1, p. 11.
Ershler, B., Discuss. Faraday Soc., 1947, vol. 1, p. 269.
Ershler, B.V., Zh. Fiz. Khim., 1948, vol. 22, p. 683.
Grafov, B.M. and Ukshe, E.A., Elektrokhimicheskie tsepi peremennogo toka (Electrochemical AC Circuits), Moscow: Nauka, 1973.
Armstrong, R.D., Bell, M.F., and Metcalfe, A.A., Chem. Soc. Spec. Periodical Rep., 1978, vol. 6, p. 98.
Gabrielly, C., Identification of Electrochemical Processes by Frequency Response Analysis: Technical Report Member. 004/83, Farnborough: Solarton, Schlumberger, 1980.
Gabrielly, C., Use and Application of Electrochemical Impedance Techniques: Technical Report Member. 004/83, Farnborough: Solarton, Schlumberger, 1990.
Sluyters-Rechbach, M. and Sluyters, J.H., Electroanalytical Chemistry: A Series of Advances, Bard, A.J., Ed., New York: Wiley, 1980.
Impedance Spectroscopy, Macdonald, J.R., Ed., New York: Wiley-Interscience, 1987.
Stoynov, Z.B., Grafov, B.M., Savova-Stoynova, B.S., and Elkin, V.V., Elektrokhimicheskii impedans (The Electrochemical Impedance), Moscow: Nauka, 1991.
Olivier, A., Merienne, E., Chopart, J.P., and Aaboubi, O., Electrochim. Acta, 1992, vol. 37, p. 1945.
Gabrielly, C., Keddam, M., and Lizee, J.F., J. Electroanal. Chem., 1993, vol. 359, p. 1.
Rotenberg, Z.A., Elektrokhimiya, 1994, vol. 30, p. 701.
Rotenberg, Z.A., Electrochim. Acta, 1997, vol. 42, p. 793.
Ambari, A., Desluis, C., and Tribollet, B., Int. J. Heat Mass Transf., 1986, vol. 29, p. 35.
Miller, B. and Bruckenstein, S., J. Electrochem. Soc., 1970, vol. 117, p. 1032.
Desluis, C. and Tribollet, B., Advances in Electrochemical Science and Engineering, Gerischer, H. and Tobias, Ch.W., Eds., New York: Pergamon, 1991, vol. 2.
Martem'yanov, S.A. and Grafov, B.M., Elektrokhimiya, 1988, vol. 29, p. 99.
Grafov, B.M., Martem'yanov, S.A., and Nekrasov, L.N., Turbulentnyi diffuzionnyi sloi v elektrokhimicheskikh sistemakh (The Turbulent Diffusion Layer in Electrochemical Systems), Moscow: Nauka, 1990.
Nernst, W., Z. Phys. Chem., Abt. A, 1904, vol. 47, p. 52.
Elkin, V.V., Mishuk, V.Ya., Alekseev, V.N., and Grafov, B.M., Elektrokhimiya, 2001, vol. 37, p. 463.
Sluyters-Rechbach, M. and Sluyters, J.H., Comprehensive Chemical Kinetics, Bamford, C.H. and Compton, R.G., Eds., New York: Elsevier, 1986, vol. 26, p. 203.
Bagotzky, V.S., Osnovy elektrokhimii (Fundamentals of Electrochemistry), Moscow: Khimiya, 1988.
Khomchenko, T.N., Martem'yanov, S.A., Nekrasov, L.N., et al., Elektrokhimiya, 1989, vol. 25, p. 1546.
Elkin, V.V., Lentsner, B.I., Abaturov, M.A., and Kuzmin, V.G., J. Electroanal. Chem., 1979, vol. 96, p. 149.
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Elkin, V.V., Grafov, B.M., Nekrasov, L.N. et al. Turbulent Electrochemical Noise: A Theoretical Analysis in the Frequency–Potential Coordinates. Russian Journal of Electrochemistry 38, 199–208 (2002). https://doi.org/10.1023/A:1016828601243
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DOI: https://doi.org/10.1023/A:1016828601243