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Turbulent Electrochemical Noise: A Theoretical Analysis in the Frequency–Potential Coordinates

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Abstract

Spectral density of random alternating current, which is induced by turbulent pulsations of electrolyte velocity in a cell, is theoretically analyzed within the Ershler–Randles charge transfer model in the Nernst diffusion layer approximation. The effect of electrode potential on the spectral current density is analyzed at various frequencies of hydrodynamic pulsations.

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Elkin, V.V., Grafov, B.M., Nekrasov, L.N. et al. Turbulent Electrochemical Noise: A Theoretical Analysis in the Frequency–Potential Coordinates. Russian Journal of Electrochemistry 38, 199–208 (2002). https://doi.org/10.1023/A:1016828601243

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