Abstract
A new approach to studying electromembrane systems by the laser interferometry method is proposed. Problems in the electrodialysis kinetics that had been solved by this method are reviewed. These include the determination of the size of diffusion boundary layers, the measurement of concentration profiles of solutions at a concentration polarization of ion-selective membranes in solutions of one and two components in isothermal and nonisothermal conditions, the verification of mathematical models for electrodialysis, and the measurement of local Sherwood numbers. A method for measuring concentration profiles in solutions at the interface with bodies of spherical symmetry following the imposition of a gradient of an electric potential on the system is offered. The results of studying the concentration polarization of an ion exchanger granules are analyzed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Vetter, K., Elektrochemische Kinetik, Berlin: Springer, 1961.
Antweiler, H.J., Z. Elektrochem., 1937, vol. 43, p. 596; 1938, vol. 44, pp. 719, 831, 888.
Spiegler, K.S., Membranes a Permeabilite Selective, Paris: CNRS, 1969.
Lerche, D. and Wolf, H., Z. Phys. Chem. (Leipzig), 1974, vol. 225, p. 126.
Sanchez, V. and Clifton, M., J. Chim. Phys. Phys.-Chim. Biol., 1980, vol. 77, pp. 413, 421.
O'Brien, R.N., Zhao, B., and Fyles, I., J. Membr. Sci., 1984, vol. 20, pp. 297, 305.
Ponomarev, M.I., Teselkin, V.V., and Grebenyuk, V.D., Khim. Tekhnol. Vody, 1985, vol. 7, p. 78.
Matysik, J., Chmiel, J., and Ciezczik-Chmiel, A., J. Chromatogr., 1985, vol. 333, p. 198.
Shaposhnik, V.A., Vasil'eva, V.I., and Praslow, D.B., J. Membr. Sci., 1995, vol. 101, p. 23.
Grebenyuk, V.D., Elektrodializ (Electrodialysis), Kiev: Tekhnika, 1976.
Shaposhnik, V.A., Kuzminykh, V.A., Grigorchuk, O.V., and Vasil'eva, V.I., J. Membr. Sci., 1997, vol. 133, p. 27.
Shaposhnik, V.A., Grigorchuk, O.V., Korzhov, E.N., et al., J. Membr. Sci., 1998, vol. 139, p. 85.
Vasil'eva, V.I., Shaposhnik, V.A., and Kesore, K., Khim. Tekhnol. Vody, 1991, vol. 13, p. 150.
McLarhou, F.R., Myller, R.H., and Tobias, C.W., J. Electrochem. Soc., 1975, vol. 122, p. 59.
Shaposhnik, V.A., Vasil'eva, V.I., and Kesore, K., Elektrokhimiya, 1991, vol. 27, p. 891.
Nikonenko, V.V., Gnusin, N.P., Zabolotskii, V.I., and Urtenov, M.Kh., Elektrokhimiya, 1985, vol. 21, p. 377.
Vasil'eva, V.I. and Shaposhnik, V.A., Elektrokhimiya, 1994, vol. 30, p. 1454.
Newman, J., Electrochemical Systems, Englewood Cliffs: Prentice-Hall, 1973.
Berezina, N.P., Shaposhnik, V.A., Praslov, D.B., and Ivina, O.P., Zh. Fiz. Khim., 1990, vol. 64, p. 2790.
Vasil'eva, V.I., Shaposhnik, V.A., Ram, S., and Praslov, D.B., Elektrokhimiya, 1991, vol. 27, p. 926.
Nikonenko, V.V., Zabolotskii, V.I., and Gnusin, N.P., Elektrokhimiya, 1979, vol. 15, p. 1494; 1980, vol. 16, p. 556.
Shaposhnik, V.A., Malygin, A.V., and Vasil'eva, V.I., Elektrokhimiya, 1997, vol. 33, p. 439.
Simons, R., Electrochim. Acta, 1984, vol. 29, p. 151.
Shaposhnik, V.A., Vasil'eva, V.I., and Reshetnikova, E.V., Elektrokhimiya, 2000, vol. 36, p. 872.
Gnusin, N.P. and Grebenyuk, V.D., Elektrokhimiya granulirovannykh ionitov (The Electrochemistry of Granulated Ionites), Kiev: Naukova Dumka, 1972.
Glueckauf, E., Br. Chem. Eng., 1959, vol. 4, p. 646.
Malykhin, M.D. and Shaposhnik, V.A., Khim. Tekhnol. Vody, 1991, vol. 13, p. 1089.
Malykhin, M.D., Shaposhnik, V.A., and Kuz'minykh, V.A., Zh. Fiz. Khim., 1992, vol. 66, p. 3382.
Shaposhnik, V.A., Malykhin, M.D., and Podobedov, A.R., Khim. Tekhnol. Vody, 1993, vol. 15, p. 104.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Vasil'eva, V.I., Shaposhnik, V.A., Grigorchuk, O.V. et al. Electrodialysis Kinetics by Laser Interferometry. Russian Journal of Electrochemistry 38, 846–852 (2002). https://doi.org/10.1023/A:1016809727673
Issue Date:
DOI: https://doi.org/10.1023/A:1016809727673