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Kinetics of the Sodium Chlorate Formation in Electrolysis of Chloride Solutions with Use of Dimensionally Stable Anodes

Russian Journal of Electrochemistry volume 37, pages 786–791 (2001)Cite this article

Abstract

The kinetics of the formation of sodium chlorate during electrolysis of chloride solutions with use of dimensionally stable anodes is studied. An analysis and calculations suggest that the experimental results are well described by the proposed set of differential equations under the assumption that the homogeneous chemical reaction of chlorate formation has second, rather than third, order by active chlorine.

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Authors and Affiliations

  1. Russian Federation Scientific Center, “Karpov Research Institute of Physical Chemistry,”, ul. Vorontsovo Pole 10, Moscow, 103064, Russia

    S. V. Evdokimov

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  1. S. V. Evdokimov
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Evdokimov, S.V. Kinetics of the Sodium Chlorate Formation in Electrolysis of Chloride Solutions with Use of Dimensionally Stable Anodes. Russian Journal of Electrochemistry 37, 786–791 (2001). https://doi.org/10.1023/A:1016774717213

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  • DOI: https://doi.org/10.1023/A:1016774717213

Keywords

  • Sodium
  • Chloride
  • Physical Chemistry
  • Differential Equation
  • Chlorine