Abstract
A new CrCoAPO-5 was synthesized under hydrothermal conditions, characterised by X-ray diffraction, scanning electron microscopy, infrared spectroscopy, energy dispersive X-ray analysis, thermogravimetric analysis, electron paramagnetic resonance and nitrogen physisorption. The CrCoAPO-5 showed catalytic activity in the liquid phase oxidation of cyclohexane at 115°C and 1 MPa of oxygen.
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S.T. Wilson,B.M. Lok,C.A. Messina,T.R. Cannan andE.M. Flannigen, ACS Symp. Ser. 218 (1982) 79.
E.M. Flanigen,M.L. Brent,L. Patton andS. Wilson, Stud. Surf. Sci. Catal. 28 (1986) 103
Y. Murakami,A. Lijima andJ.W. Ward, Pure Appl. Chem. 58 (1986) 1351.
Y. Xu,P. Maddox andJ.M. Thomas, Polyhedron 8 (1988) 819.
V. Murugegesan,V. Krishnasamy andS.P. Elangova, Bull. Chem. Soc. Jpn. 68 (1995) 659.
R. Howe andS. Thomson, Phys. Chem. Chem. Phys. 1 (1999) 615.
R.A. Sheldon,M. Wallau,I.W.C.E. Arends andU. Schuchardt, Acc. Chem. Res. 31 (1998) 485.
J.M. Thomas,R. Raja andG. Sankar, Catal. Lett. 55 (1998) 15.
R.A. Sheldon,I.W.C.E. Arends andH.E.B. Lempers, Catal. Today 41 (1998) 387.
I. Belkhir,A. Germain,F. Fajula andE. Fache, J. Chem. Soc. Faraday Trans. 94 (1998) 1761.
P.A. Jacobs andD.L. Vanoppen, Catal. Today 49 (1999) 177.
M. Hartmann andL. Kevan, Chem. Rev. 99 (1999) 635.
B.M. Weckhuysen,R.R. Rao,J.A. Martens andR.A. Schoonheydt, Eur. J. Inorg. Chem. 1 (1999) 565.
M.P. Kapoor andA. Raj, J. Chem. Soc. Chem. Commun. (1999) 1409.
S. Han andG. Yu, Jilin Daxue Ziran Kexue Xuebao 3 (1990) 110; Chem. Abs. 114 209903.
S. Han,L. Wang andG. Yu, Gaodeng Xuexiao Huaxue Xuebaa 11 (1990) 1171; Chem. Abs. 114 177060.
P. Concepción,A. Corma,J.M. López andJ. Pérez-Pariente, Appl. Catal. 143 (1996) 17.
E. Flanigen, US Patent 4759919(1986); E. Flanigen and S. Wilson, US Patent 4567029 (1986).
D.L. Vanoppen,D. De Vos andP.A. Jacobs, J. Catal. 177 (1998) 22.
W.M. Meier,D.H. Olson andCh. Baerlocher, Atlas of Zeolite Structure Types, Vol. 26 ( Elsevier, Amsterdam, 1996 ).
J. Kornatowski,G. Zadrozna,J. Wloch andM. Rozwadowski, Langmuir 15 (1999) 5863.
K.S.W. Sing,D.H. Everret,R.A.W. Haul,L. Moscou,R.A. Pierotti,J. Rouquérol andT. Siemieniewska, Pure Appl. Chem. 57 (1985) 603.
B. Duncan,M. Stocker,D. Gwinup,R. Szostak andK. Vinje, Bull. Soc. Chim. Fr. 129 (1992) 98.
A. Verberckmoes,B.M. Weckhuysen andR.A. Schoonheydt, Micropor. Mesopor. Mater. 22 (1998) 165.
B.M. Weckhuyse andR.A. Schoonheydt, Stud. Surf. Sci. Catal. 84 (1994) 965.
L. Kevan,V. Kurshev,D.J. Parillo,C. Pereira,G.T. Kokotailo andR.J. Gorte, J. Phys. Chem. 98 (1994) 10160.
S. Thomson,R. Howe andV. Luca, Phys. Chem. Chem. Phys. 1 (1999) 615.
A. Onopchenko andD. Schulz, J. Org. Chem. 38 (1973) 3729; J.Y. Scott and W. Chester, J. Phys. Chem. 76 (1972); G.E. Zaikov and Z. Maizus, Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.) (1969) 267.
D. Vanoppen,D. De Vos,M. Genet andP.A. Jacobs, Angew. Chem. Int. Ed. Engl. 34 (1995) 560.
M. Constantini, N. Crenne, M. Jouffret and J. Nouvel, US Patent 3923895 (1975).
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Masters, A.F., Beattie, J.K. & Roa, A.L. Synthesis of a CrCoAPO-5(AFI) Molecular Sieve and Its Activity in Cyclohexane Oxidation in the Liquid Phase. Catalysis Letters 75, 159–162 (2001). https://doi.org/10.1023/A:1016763224751
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DOI: https://doi.org/10.1023/A:1016763224751