Abstract
Catalysts represent the oldest commercial application of nanotechnology. It is suggested that the focus of catalysis research in the 21st century should be on achieving 100% selectivity for the desired product (clean manufacturing). The molecular ingredients of selectivity are not well understood. The electronic and atomic structures of nanoclusters should be investigated as a function of their size. Because of the facile restructuring of metal clusters under reaction conditions they have to be characterized in situ. New synthetic methods need to be developed to produce catalyst particles with the same size, structure and location on the support.
Similar content being viewed by others
References
G.A. Somorjai, Introduction to Surface Chemistry and Catalysis (Wiley, New York, 1994).
S.M. Davis, F. Zaera and G.A. Somorjai, J. Am. Chem. Soc. 104 (1982) 7455.
F. Zaera and G.A. Somorjai, Langmuir 2 (1986) 686.
D.J. Dwyer and G.A. Somorjai, J. Catal. 56 (1979) 249.
J. Weitkamp, S. Ernst and L. Puppe, in: Shape-Selective Catalysis in Zeolites in Catalysis and Zeolites, eds. J. Weitkamp and L. Puppe (Springer, Berlin, 1999) p. 327.
A.B. Boffa, C. Lin, A.T. Bell and G.A. Somorjai, Catal. Lett. 27 (1994) 243.
R. Kubo, J. Phys. Soc. Jpn. 17 (1962) 975.
R. Kubo, J. de Physique Coll. 2 (1977) C2–69.
I.J. Friedel, Ann. Phys. 1 (1976) 257.
I.J. Friedel, J. de Physique Coll. 2 (1977) C2–1.
D.C. Ralph, C.T. Black and M. Tinkham, Phys. Rev. Lett. 74 (1995) 3241.
R.C. Baetzold, Inorg. Chem. 20 (1981) 118.
A.E. Shilov, in: XVII ICCC, Hamburg, 1976, p. 181.
A.E. Shilov, Metal Complexes in Biomimetic Chemical Reactions (CRC Press, Boca Raton, FL, 1997).
E.A. Rohlfing, D.M. Cox and A. Kaldor, J. Phys. Chem. 88 (1984) 4497.
D.W. Powers, S.G. Hansen, M.E. Geusic and D.L. Michalopoulos, J. Chem. Phys. 78 (1983) 1983.
B.D. Leskiw and A.W. Castleman Jr., Chem. Phys. Lett. 316 (2000) 31.
D.J. Trevor, D.M. Cox and A. Kaldor, J. Am. Chem. Soc. 112 (1990) 3742.
D.M. Cox, A. Kaldor, P. Fayet, W. Eberhardt, R. Brickman, R. Sherwood, Z. Fu and D. Sodericher, ACS Symp. Ser. 437 (1990) 173.
P. Chini, J. Organometallic Chem. 200 (1980) 37.
T.S. Ahmadi, Z.L. Wang, T.C. Green, A. Henglein and M.A. El-Sayed, Science 272 (1996) 1924.
M.A. El-Sayed, Acc. Chem. Res. 34 (2001) 257.
M.A. Van Hove and G.A. Somorjai, Catal. Lett. 1 (1988) 433.
G.A. Somorjai, J. Phys. Chem. 94 (1990) 1013.
G.A. Somorjai, Catal. Lett. 7 (1990) 169.
G.A. Somorjai, Langmuir 7 (1991) 3176.
G.A. Somorjai, Ann. Rev. Phys. Chem. 45 (1994) 721.
P. Braunstein, C. deMeric de Bellefon, S.-E. Bouaoud, D. Grandjean, J.-F. Malet and J.-Y. Saillard, J. Am. Chem. Soc. 113 (1991) 5282.
I. Moiseev, J. Organometallic Chem. 488 (1995) 183.
J.N. Peters, M.H.B. Stowell, S.M. Soltis, M.G. Finnegan, M.K. Johnson and D.C. Rees, Biochem. 36 (1997) 1181.
D.C. Rees and J.B. Howard, Curr. Opin. Chem. Biol. 4 (2000) 559.
M.W.W. Adams, Biochim. Biophys. Acta 1020 (1990) 115.
C.B. Murray, C.R. Kagan and M.G. Bawendi, Annu. Rev. Mater. Sci. 30 (2000) 545.
P. Alivisatos, Nature 404 (2000) 59.
P. Wiseman, Petrochemicals (Halsted, New York, 1986).
G. Schmid, ed., Clusters and Colloids: From Theory to Applications (VCH, New York, 1994).
J.D. Aiken III and R.G. Finke, J. Mol. Catal. A 145 (1999) 1.
M.N. Vargaftik, V.P. Zagorodnikov, I.P. Stolyarov, I.I. Moiseev, V.A. Likhopobov, D.I. Kochubey, A.L. Chuvilin, V.I. Zaikovsky, K.I. Zamaraeev and G.I. Timofeeva, J. Chem. Soc. Chem. Commun. (1985) 937.
J.D. Aiken III, Y. Lin and R.G. Finke, J. Mol. Catal. A 114 (1996) 29.
G. Schmid, V. Maihack, F. Lantermann and S. Peschel, J. Chem. Soc. Chem. Commun. 589 (1996).
J.S. Bradley, G.H. Via, L. Benneviot and E.W. Hill, Chem. Mater. 8 (1996) 1895.
G. Rupprechter, A.S. Eppler, A. Avoyan and G.A. Somorjai, in: Proc. 12th ICC (Stud. Surf. Sci. Catal.) (1993).
A.S. Eppler, J. Zhu, E.A. Anderson and G.A. Somorjai, Topics Catal. 13 (2000) 33.
F.G. Menon, Chem. Rev. 94 (1994) 1021.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Somorjai, G., Borodko, Y. Research in Nanosciences – Great Opportunity for Catalysis Science. Catalysis Letters 76, 1–5 (2001). https://doi.org/10.1023/A:1016711323302
Issue Date:
DOI: https://doi.org/10.1023/A:1016711323302