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Chromatographic Determination of Polyiodohalides of Organic Nitrogen Bases

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Abstract

The following biologically active polyiodohalides of organic nitrogen bases were synthesized and studied: trimethylbenzylammonium, triethylbenzylammonium, and N-cetylpyridinium diiodochlorides; tetramethylammonium, tetrabutylammonium, and N-cetylpyridinium diiodobromides; and butylcholinium triiodide. A method for the identification of the above compounds was proposed based on the dependence of their thin-layer chromatographic mobility and IR, UV, and NMR spectrometric properties and on the nature of the organic cation and the structure of the polyiodide anion. Reversed-phase high-performance liquid chromatography in a 1 : 1 methanol–water mixture (pH 6.86) was used for determining the compounds under study. The developed procedure is characterized by high sensitivity (0.09–0.51 μg) at RSD of no worse than 10%.

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Authors and Affiliations

  1. Department of Chemistry, Rostov State University, ul. Zorge 7, Rostov-on-Don, 344090, Russia

    M. S. Chernov'yants, V. E. Gol'eva & I. V. Evlashenkova

  2. Institute of Physical and Organic Chemistry, Rostov State University, pr. Stachki 194/3, Rostov-on-Don, 344090, Russia

    A. I. Pyshchev

Authors
  1. M. S. Chernov'yants
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  2. V. E. Gol'eva
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  3. A. I. Pyshchev
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  4. I. V. Evlashenkova
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Chernov'yants, M.S., Gol'eva, V.E., Pyshchev, A.I. et al. Chromatographic Determination of Polyiodohalides of Organic Nitrogen Bases. Journal of Analytical Chemistry 56, 815–818 (2001). https://doi.org/10.1023/A:1016700127238

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  • DOI: https://doi.org/10.1023/A:1016700127238

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