Abstract
Calculations of near-electrode concentrations of reactant ions and their variations with time during electrodeposition of binary alloys with a modulated-over-thickness composition are presented for various types of pulsed electrolysis. Thicknesses of pure components and alloys of variable compositions at various ratios between component concentrations and pulse magnitudes are established. The role played by exaltation effects, alloying, crystallization factors, and dissolution of the electronegative component from the alloy in a next pulse is shown.
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Gamburg, Y.D. Electrodeposition of Alloys with Composition Modulated over Their Thickness: A Review. Russian Journal of Electrochemistry 37, 585–590 (2001). https://doi.org/10.1023/A:1016662316553
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DOI: https://doi.org/10.1023/A:1016662316553