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Kinetics of Electrochemical Processes under Conditions of a Slow Chemical Reaction in Solution

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Abstract

The kinetics of electrochemical processes under the conditions of a slow chemical reaction in solution is analyzed in a general form, which admits a change in their limiting stages. The main feature of polarization curves for the electrochemical processes is the existence of two Tafel portions with slopes corresponding to a slow homogeneous chemical reaction (lower portion) and a preceding faster electrochemical stage (upper portion with a higher slope).

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REFERENCES

  1. Vetter, K., Elektrochemische Kinetik, Berlin: Springer, 1961.

    Google Scholar 

  2. Damaskin, B.B. and Petrii, O.A., Vvedenie v elektrokhimicheskuyu kinetiku (Electrochemical Kinetics: An Introduction), Moscow: Vysshaya Shkola, 1975, p. 319.

    Google Scholar 

  3. Bagotzky, V.S., Osnovy elektrokhimii (Fundamentals of Electrochemistry), Moscow: Khimiya, 1988, p. 272.

    Google Scholar 

  4. Antropov, L.I., Teoreticheskaya electrokhimiya (Theoretical Electrochemistry), Moscow: Vysshaya Shkola, 1984, p. 324.

    Google Scholar 

  5. Rotinyan, A.L., Tikhonov, K.I., and Shoshina, I.A., Teoreticheskaya elektrokhimiya (Theoretical Electrochemistry), Leningrad: Khimiya, 1981, pp. 268, 302.

    Google Scholar 

  6. Kokoulina, D.V. and Krishtalik, L.I., Elektrokhimiya, 1971, vol. 7, p. 346.

    Google Scholar 

  7. Kheifets, L.I., Gol'dberg, A.B., and Mazanko, A.F., Itogi Nauki Tekh., Ser.: Elektrokhimiya, 1983, vol. 19, p. 244.

    Google Scholar 

  8. Yakimenko, L.M. and Seryshev, G.A., Elektrokhimicheskii sintez neorganicheskikh soedinenii (Electrochemical Synthesis of Inorganic Compounds), Moscow: Khimiya, 1984, p. 35.

    Google Scholar 

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Evdokimov, S.V. Kinetics of Electrochemical Processes under Conditions of a Slow Chemical Reaction in Solution. Russian Journal of Electrochemistry 37, 575–578 (2001). https://doi.org/10.1023/A:1016658215645

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  • DOI: https://doi.org/10.1023/A:1016658215645

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