Abstract
The electroconductivity, viscosity, and density of 1 M LiClO4solutions in sulfolane mixed with 1,2-dimethoxyethane are measured. Some of the measured quantities deviate from additivity. A maximum of LiClO4electroconductivity in the mixture occurs at a 1 : 2 molar ratio of sulfolane to dimethoxyethane. The electroconductivity increase is presumably due to improved transport properties of the system.
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REFERENCES
Kolosnitsyn, V.S., Sheina, L.V., Karichkovskaya, N.V., and Mochalov, S.E., Zh. Fiz. Khim. 1999, vol. 63, p. 112.
Song, J.Y., Wang, Y.Y., and Wan, C.C., J. Power Sources 1999, vol. 77, p. 183.
Kolosnitsyn, V.S., Slobodchikova, N.V., and Sheina, L.V., Zh. Prikl. Khim. (St. Petersburg), 2000, vol. 36, p. 1089.
Karapetyan, Yu.A. and Eichis, V.N., Fiziko-khimicheskie svoistva elektrolitnykh nevodnykh rastvorov (Physicochemical Properties of Nonaqueous Electrolytes), Moscow: Khimiya, 1989.
Orliukas, A., Kenzenis, A., Mikucenis, V., and Vaitkus, R., Elektrokhimiya 1987, vol. 23, p. 98.
Anosov, V.Ya., Ozerova, M.I., and Fialkov, Yu.Ya., Osnovy fiziko-khimicheskogo analiza (Fundamentals of Physicochemical Analysis), Moscow: Nauka, 1978.
Dubasova, V.S., Karapetyan, A.V., and Kundirenko, D.B., Available form Ukr. NIINTI, Kiev, 1987, no. 2209.
Matsuda, Y., Nakashima, H., Morita, M., and Takasu, Y., J. Electrochem. Soc. 1981, vol. 128, p. 2552.
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Kolosnitsyn, V.S., Slobodchikova, N.V., Mochalov, S.E. et al. Electroconductivity of Lithium Perchlorate Solutions in Sulfolane Mixtures with 1,2-Dimethoxyethane. Russian Journal of Electrochemistry 37, 632–634 (2001). https://doi.org/10.1023/A:1016630904258
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DOI: https://doi.org/10.1023/A:1016630904258