Abstract
The new silver(I) triple salt 2Ag2C2·AgF·9AgNO3·H2O was prepared by dissolving Ag2C2 in an aqueous solution of AgNO3 and AgBF4. Its crystal structure contains two kinds of monocapped trigonal prismatic C2@Ag7 cages, with the capping atom occurring on one triangular face or one rectangular face.
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Wang, QM., Mak, T.C.W. Coexistence of Differently Capped Trigonal Prismatic C2@Ag7 Cages in a Triple Salt of Silver(I) Acetylide. Journal of Cluster Science 12, 391–398 (2001). https://doi.org/10.1023/A:1016621117548
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DOI: https://doi.org/10.1023/A:1016621117548