Abstract
Addition of Gd to Co/SiO2 Fischer–Tropsch synthesis catalysts (1) increases reducibility to Co metal, (2) decreases CH4 selectivity, (3) increases activity for CO hydrogenation based on the mass of Co, and (4) causes carbon deposition at lower temperatures when compared to the unpromoted catalyst. The intrinsic activity, based on H2 chemisorption surface area, is the same for both unpromoted and promoted catalysts.
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G.W. Huber,T.L. Conrad,K.W. Woolley,C.G. Guymon andC.H. Bartholomew, Prepr. Petr. Chem. Am. Chem. Soc. 45 (2000) 260.
A.R. Belambe,R. Oukaci andJ.G. Goodwin, J. Catal. 166 (1997) 8.
H.F.J. van't Blik,D.C. Koningsberger andR. Prins, J. Catal. 97 (1986) 210.
L.A. Bruce,M. Hoang,A.E. Hughes andT.W. Turney, Appl. Catal. A 100 (1993) 51.
L. Guczi,R. Sundararajan,Z. Kippany,Z. Zsoldos,Z. Schay,F. Mizukami andS. Niwa, J. Catal. 167 (1997) 482.
E. Iglesia,S.L. Soled,R.A. Fiato andG.H. Via, J. Catal. 143 (1993) 345.
E. Iglesia,S.L. Soled andR.A. Fiato, J. Catal. 137 (1992) 212.
A. Kogelbauer,J.G. Goodwin andR. Oukaci, J. Catal. 160 (1996) 125.
D. Schanke,S. Vada,E.A. Blekkan,A.M. Hilmen,A. Hoff andA. Holmen, J. Catal. 156 (1995) 85.
S. Vada,A. Hoff,E. Adnanes,D. Schanke andA. Holmen, Topics Catal. 2 (1995) 155.
C.H. Bartholomew, in: New Trends in CO Activation, Stud. Surf. Sci. Catal., Vol. 64, ed. L. Guczi (Elsevier, Amsterdam, 1991) p. 158.
H. Beuther, C.L. Kibby, T.P. Kobylinski and R.B. Pannell, US Patent 4399234 (1983), assigned to Gulf Research and Development Company.
H. Beuther, C.L. Kibby, T.P. Kobylinski and R.B. Pannell, US Patent 4413064 (1983), assigned to Gulf Research and Development Company.
M.D. Mitchel andM.A. Vannice, Ind. Eng. Chem. Fundam. 23 (1984) 88.
R.F. Hicks andA.T. Bell, J. Catal. 91 (1984) 104.
C. Sudhakar andM.A. Vannice, J. Catal. 95 (1985) 227.
J.S. Rieck andA.T. Bell, J. Catal. 99 (1986) 278.
B.A. Sexton,A.E. Hughes andT.W. Turney, J. Catal. 97 (1986) 390.
B. Viswanathan andR. Gopalakrishnan, J. Catal. 99 (1986) 342.
C.H. Mauldin, S.M. Davis and K.B. Arcuri, US Patent 4719240 (1988), assigned to Exxon Research and Engineering Co.
C.H. Mauldin, S.M. Davis and K.B. Arcuri, US Patent 4762959 (1988), assigned to Exxon Research and Engineering Co.
R.A. Fiato, R. Bar-Gadda and S. Miseo, US Patent 419240 (1988), assigned to Exxon Research and Engineering Co.
T. Shido andY. Iwasawa, J. Catal. 137 (1992) 267.
S. Vada,B. Chen andJ.G. Goodwin, J. Catal. 153 (1995) 224.
G.W. Huber, C.C. Guymon and C.H. Bartholomew, in preparation (2001).
R.D. Jones andC.H. Bartholomew, Appl. Catal. 39 (1988) 77.
R.C. Reuel andC.H. Bartholomew, J. Catal. 85 (1980) 63.
C.H. Bartholomew andR.B. Panell, J. Catal. 65 (1980) 390.
R. Zennaro,M. Tagliabue andC.H. Bartholomew, Catal. Today 58 (2000) 309.
A.Y. Khodakov,J. Lynch,D. Bazin,B. Rebours,N. Zanier,B. Moisson andP. Chaumette, J. Catal. 168 (1997) 16.
K.C. Vranken,K. Possemiers,P.V.D. Voort andE.F. Vansant, Colloids Surf. A 98 (1995) 235.
C.C. Liu andG.E. Maciel, J. Am. Chem. Soc. 118 (1996) 5103.
G.W. Huber, Masters thesis, Brigham Young University (2000).
G.W. Huber, C.G. Guymon, B.C. Stephenson and C.H. Bartholomew, in preparation (2001).
C.H. Bartholomew, Catal. Lett. 7 (1990) 27.
F.H. Ribeiro,A.E.S. von Wittenau,C.H. Bartholomew andG.A. Somorjai, Catal. Rev. Sci. Technol. 39 (1997) 49.
C.H. Bartholomew,G.D. Weatherbee andG.A. Jarvi, Chem. Eng. Commun. 5 (1980) 125.
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Huber, G.W., Butala, S.J., Lee, M.L. et al. Gd promotion of Co/SiO2 Fischer–Tropsch synthesis catalysts. Catalysis Letters 74, 45–48 (2001). https://doi.org/10.1023/A:1016613627261
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DOI: https://doi.org/10.1023/A:1016613627261