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N2O Decomposition over Fe/ZSM-5: Effect of High-Temperature Calcination and Steaming

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Abstract

N2O decomposition over Fe/ZSM-5 made by the sublimation method was investigated. Further calcination or steaming treatment (700°C) increased the decomposition rate of N2O. FTIR showed that such treatments lead to the disappearance of Brønsted acid sites. The various catalysts have different apparent activation energies, confirming the presence of different active Fe species. The observation that after high-temperature calcination a higher activity is obtained while no dealumination occurs indicates a mechanism where neutral Fe oxide clusters occluded in the zeolite micropores react at high temperature with the zeolite protons to form [FeO]+-like species.

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Authors and Affiliations

  1. Schuit Institute of Catalysis, Laboratory of Inorganic Chemistry and Catalysis, Eindhoven University of Technology, P.O. Box 513, 5600 MB, Eindhoven, The Netherlands

    Q Zhu, B.L. Mojet, E.J.M. Hensen, J. van Grondelle, P.C.M.M. Magusin & R.A. van Santen

  2. Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB, Eindhoven, The Netherlands

    R.A.J. Janssen

Authors
  1. Q Zhu
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  2. B.L. Mojet
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  3. R.A.J. Janssen
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  4. E.J.M. Hensen
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  6. P.C.M.M. Magusin
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  7. R.A. van Santen
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Zhu, Q., Mojet, B., Janssen, R. et al. N2O Decomposition over Fe/ZSM-5: Effect of High-Temperature Calcination and Steaming. Catalysis Letters 81, 205–212 (2002). https://doi.org/10.1023/A:1016581107432

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