Abstract
Benzene and maleic anhydride react over solid acids, viz. CrO3/Magnesol and SO4 2-/ZrO2 catalysts to form phthalic anhydride and olefins, which in turn produce phthalate esters as end products. Based on the product distribution, a reaction pathway is proposed.
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REFERENCES
Y.V. Subba Rao, S.J. Kulkarni, M. Subrahmanyam, A.V. Rama Rao: Appl. Catal., 133, 641 (1995).
P. Rami Reddy, M. Subrahmanyam, V. Durga Kumari: Catal. Lett., 61, 207 (1999).
V. Durga Kumari, K.V.V.S.B.R.B.S. Murthy, M. Subrahmanyam, K.S. Patil, P. Kanta Rao: Catalysis: Modern Trends, Proc. 12th National Symposium on Catalysis, Bombay, India, 328, 1995.
V. Durga Kumari, G. Saroja, A.Ratnamala, M.Subrahmanyam, Communicated.
Jap. Pat., 82,70,833 (1982) to Mitsui Totatsu Chemicals: Chemical Abstracts , 97, 127303j.
Eur.Pat., 306,940 (1989) to Yokoyama Yoshio: Chem. Abstr, 111, 59971f.
V. Durga Kumari, S. Narayanan: J. Mol. Catal., 65, 385 (1991).
V. Durga Kumari: React. Kinet. Catal. Lett., 54, 1, 137 (1995).
J. Yinon: Org. Mass Spectrum, 23, 755 (1988).
T.D. Radhakrishan Nair: Thermochim. Acta, 182, 337 (1991).
Z. Sarbak: Appl. Catal., 124, 245 (1995).
M. Kantcheva, I.G. Dalla Lana, A. Szymura: J. Catal., 154, 329 (1995).
M.A. Coelho, D.E. Resasco, E.C. Sikabwe, R.L. White: Catal. Lett., 32, 253 (1995).
A. Ghenciu, D. Farcasiu: J. Mol. Catal. A, 109, 273 (1996).
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Durga Kumari, V., Rachel, A., Ratnamala, A. et al. Vapor phase synthesis of phthalate esters from benzene and maleic anhydride over CrO3/magnesol and SO4 2-/ZrO2 + . Reaction Kinetics and Catalysis Letters 76, 221–225 (2002). https://doi.org/10.1023/A:1016567424000
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DOI: https://doi.org/10.1023/A:1016567424000