Abstract
The adsorption properties of carbon-fiber busofite-type materials with respect to molecular iodine I2 and methyl iodide CH3I are investigated. It is shown that compared with SKT-3 activated carbon the efficiency of molecular iodine removal from air using busofite is 3 times higher and the efficiency for methyl iodide is 1.7 times higher. For busofite impregnated with 1–3 mass% KI, TEDA, or AgNO3 the efficiency of removal of CH3 131I (no carrier) increases by a factor of 2 and reaches 96–99.5% for 1–3 layers of busofite. The dynamical capacity of busofite with respect to CH3I is 8.5–10 mg/cm2 (∼250 mg/g), and the contact time on the first layer of the material is ≥0.08 sec.
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REFERENCES
F. I. Nakhutin, D. V. Ochkin, N. M. Smirnova, et al., Purification of Gases and Monitoring of Gaseous Emissions From Nuclear Power Plants, Énergoatomizdat, Moscow (1983).
Yu. V. Chechetkin, E. K. Yakshin, and V. M. Eshcherkin, Purification of Radioactive Gaseous Wastes from Nuclear Power Plants, Énergoatomizdat, Moscow (1986).
V. V. Badyaev, Yu. A. Egorov, and S. V. Kazakov, Protection of the Environment During Operation of Nuclear Power Plants, Énergoatomizdat, Moscow (1990).
V. G. Kritskii, N. I. Ampelogova, V. I. Lebedev, S. M. Kovalev, et al., “Analysis of the efficiency of iodine carbon adsorbers in special ventillation systems in nuclear power plants with RBMK-1000,” At. Énerg., 83, No. 1, 44 (1997).
N. I. Ampelogova, V. G. Kritskii, S. M. Kovalev, et al., “Adsorption of molecular iodine and methyl iodine vapors from air,” Zh. Prikl. Khim., 73, No. 8 (2000).
L. M. Sharygin, S. Ya. Tret'yakov, E. I. Zlokazova, et al., “High-temperature removal of molecular iodine and methyl iodine from gases by inorganic sorbent based on titanium dioxide,” At. Énerg., 73, No. 4, 312 (1992).
L. M. Sharygin, S. Ya. Tret'yakov, E. I. Zlokazova, et al., “High-temperature removal of methyl iodide from steam-air flows by inorganic sorbent based on titanium dioxide,”ibid., 82, No. 6, 424 (1997).
Siloxide Sorbent, TU LKVSh 94.373.00.000.
H. Dillman and J. Wilhelm, “Design of a containment venting filter system for PWRs,” in: IAEA-TEC-DOC-776, Vienna (1991).
B. I. Styro, T. N. Nedvetskaite, and V. I. Filistovich, Iodine Isotopes and Radiation Safety, Gidrometeoizdat, St. Petersburg (1992).
Sorption-Filtering Material FPUA-70-7,0. TU 2282-251-02100232-97, Russian Science Center L. Ya. Karpov Scientific-Research Physicochemical Institute.
Filosorb-A Filtering Sorption Material, TU 6 96800-010-00210234-99.
FAI-3000/2 Antiiodine Filter-Adsorber for Nuclear Power Plants, TU 95 2753-2000.
R. M. Levit, Electrically-Conducting Chemical Fibers, Khimiya, Moscow (1986).
I. N. Ermolenko, I. P. Lyubliner, and N. V. Gul'ko, Element-Containing Carbon Fiber Materials, Nauka i Tekhnika, Minsk (1982).
L. G. Didenko and A. G. Fat'kin, “On the physicochemical forms of 131I in gas-aerosol emissions from the Belarus nuclear power plant,” in: Radiation Safety and Protection of Nuclear Power Plants (1995), No. 9, p. 146.
V. G. Kritskii, N. I. Ampelogova, V. I. Krupennikova, et al., Russian Patent No. 2161338, October 2000.
V. I. Lebedev, S. M. Kovalev, V. G. Kritskii, et al., “Radioecological aspects of handling of radioactive wastes at the Leningrad nuclear power plant,” Ékolog. At. Énerget., No. 2, 60 (1998).
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Ampelogova, N.I., Kritskii, V.G., Krupennikova, N.I. et al. Carbon-Fiber Adsorbent Materials for Removing Radioactive Iodine from Gases. Atomic Energy 92, 336–340 (2002). https://doi.org/10.1023/A:1016558127710
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DOI: https://doi.org/10.1023/A:1016558127710