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Kinetic equation for reversible heterogeneous catalytic reactions

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Abstract

It is demonstrated that when operating far from equilibrium, despite the non-linearity of a complex reaction system, the overall rate of a heterogeneous catalytic reaction is expressed by a classical equation, where the equilibrium constant is determined by the ratio of constants of the forward and reverse reaction, which do not include the lateral interactions in the adsorbed layer.

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Authors and Affiliations

  1. Laboratory of Industrial Chemistry, Åbo Akademi University, Biskopsgatan 8, FIN-20500, Åbo, Finland

    Dmitry Yu. Murzin

  2. Karpov Institute of Physical Chemistry, Vorontsovo pole 10, Moscow, 103064, Russia

    Michail G. Slin"ko

Authors
  1. Dmitry Yu. Murzin
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  2. Michail G. Slin"ko
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Murzin, D.Y., Slin"ko, M.G. Kinetic equation for reversible heterogeneous catalytic reactions. Reaction Kinetics and Catalysis Letters 76, 369–374 (2002). https://doi.org/10.1023/A:1016556516248

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