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Ethanol decomposition over Pd-based catalyst in the presence of steam

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Abstract

Catalytic decomposition of ethanol in the presence of steam over Pd supported on a porous carbonaceous material was studied. XPS and TEM were used for the catalyst characterization. Experiments were performed under atmospheric pressure, temperature of 320-360°C and H2O/C2H5OH molar ratio 8.1. It was found that the catalyst exhibited a high activity and long-term stability for the ethanol decomposition into a gas mixture containing carbon oxides, methane and hydrogen.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia

    V.V. Galvita, V.D. Belyaev, V.A. Semikolenov & V.A. Sobyanin

  2. Department of Mechanical and Industrial Engineering, University of Thessaly Pedion Areos, 38334, Volos, Greece

    P. Tsiakaras

  3. Novosibirsk State University, Novosibirsk, 630090, Russia

    A. Frumin

Authors
  1. V.V. Galvita
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  2. V.D. Belyaev
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  3. V.A. Semikolenov
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  4. P. Tsiakaras
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  5. A. Frumin
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  6. V.A. Sobyanin
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Galvita, V., Belyaev, V., Semikolenov, V. et al. Ethanol decomposition over Pd-based catalyst in the presence of steam. Reaction Kinetics and Catalysis Letters 76, 343–351 (2002). https://doi.org/10.1023/A:1016500431269

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  • DOI: https://doi.org/10.1023/A:1016500431269

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