Abstract
A review of literature data is presented on experimental and theoretical investigations of carbon and solid-fuel gasification in various gas media at high temperatures (up to 1373 K). Methods of experimental and theoretical investigations are described. A theoretical formulation of the problem of nonstationary gasification of carbon is presented. The value of the real kinetic constant of carbon gasification by carbon dioxide is given. Key words: carbon, carbon dioxide, active areas, nonstationary gasification, kinetic constant.
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REFERENCES
A. S. Predvoditelev, L. N. Khitrin, O. A. Tsukhanova, et al., Combustion of Carbon [in Russian], Izd. Akad. Nauk SSSR, Moscow (1949).
L. N. Khitrin, Physics of Combustion and Explosion [in Russian], Izd. Mosk. Univ., Moscow (1957).
B. V. Kantorovich, Fundamentals of the Theory of Combustion and Gasification of a Solid Fuel [in Russian], Izd. Akad. Nauk SSSR, Moscow (1958).
D. A. Frank-Kamenetskii, Diffusion and Heat Transfer in Chemical Kinetics [in Russian], Nauka, Moscow (1967).
N. R. Leine, F. Y. Vastola, and P. L. Walker, “The importance of active surface area in the carbonoxygen reaction," J. Phys. Chem., 67, No. 10, 2030–2034 (1969).
A. Lizzo, Jiang Hong, and R. Radovic, “On the kinetics of carbon (char) gasification: Reconciling model with experiments," Carbon, 28, No. 1, 7–19 (1990).
O. W. Fritzland and K. Y. Huttinger, “Active sites and intrinsic rates of carbon-gas reaction," Carbon, 31, No. 6, 923–938 (1993).
E. S. Golovina and A. A. Klimov, “On the true kinetic constant of the heterogeneous C+CO2 gasification reaction," Combust. Expl. Shock Waves, 35, No. 4, 393–396 (1999).
L. N. Khitrin, “Nonstationary diffuse-kinetic processes in heterogeneous systems," Khim. Tverd. Tela, No. 6, 110–117 (1967).
E. S. Golovina, “Diffusion coefficient of a gas in carbon," Dokl. Akad. Nauk SSSR, TXXXV, No. 1, 141–144 (1952).
Abstracts of the 27th Int. Symp. on Combustion (University of Colorado at Boulder, August 2–7, 1998), The Combustion Inst., Pittsburgh (1999).
Chemical Physics of Combustion and Explosion Processes, XII Symp. on Combustion and Explosion (September 10–15, 2000), Chernogolovka (2000).
V. I. Babii, D. V. Bulanov, and V. P. Artem'ev, “Macrokinetic constants of the process of decomposition of NO, CO2, and H2O in a reducing dusty medium," in: Proc. XII Symp. on Combustion and Explosion, Technology, Chernogolovka (2000), p. 120.
A. P. Borisov, G. I. Skachkov, and K. Ya. Troshin, “Kinetics of ignition and combustion of the simplest hydrocarbon fuels C1 - C3 in air mixtures," Khim. Fiz., 18, No. 9, 45 (1999).
M. H. N. Matsunaga, N. N. Marinov, and W. J. Pitz, “An experimental and kinetic calculation of the promotion effect of hydrocarbons on the NO-NO2 conversion in a flow reaction," in: Abstracts of the 27th Int. Symposium on Combustion, The Combustion Inst., Pittsburgh (1999), p. 119.
A. Carlos and Veras Cugel, “Effect of petrole size and pressure on the conversion on fuel N into NO in the boundary layer during devolatilization stage of combustion," ibid., p. 11.
P. Chambrien, T. Kyatani, and A. Tamita, “C-NO reaction in the presence of O2,” ibid., p. 12.
I. Aarne and E. M. Sunberg, “A study of the reaction order of the NO-carbon gasification reaction," ibid., p. 13.
P. J. Achman and B. S. Haynes, “The rate of charnitrogen in low temperature oxidation," ibid., p. 19.
J. M. Veranth, D. W. Pershing, and A. Sarafim, “Sources of unburdened carbon in the lay ash produced from low-NOx pulverized coal combustion," ibid., p. 36.
Guo Feng, W. C. Hecker, et al., “Kinetic of NO reaction by char: Effects of coal Ra," ibid., p. 78.
N. M. Marinov, W. J. Pitz, et al., “Chemical kinetic modelling of a methane opposed plow diffusion flame and comparison to experiment," ibid., p. 41.
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Golovina, E.S. Investigation of Heterogeneous Combustion and Gasification of Carbon and Solid Fuel (Review). Combustion, Explosion, and Shock Waves 38, 401–408 (2002). https://doi.org/10.1023/A:1016298813255
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DOI: https://doi.org/10.1023/A:1016298813255