Skip to main content
Log in

Phase Transition of ZrH2.3

  • Published:
Inorganic Materials Aims and scope

Abstract

The state of hydrogen in tetragonal ε-ZrH2.3 was probed by 1H nuclear magnetic resonance spectroscopy. Both the resonance width and Knight shift were found to exhibit anomalies around 380 K, which were interpreted as evidence for a structural phase transition involving hydrogen ordering.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. Metal Hydrides, Mueller, W.M., Blackledge, J.P., and Libowitz, G.G., Eds., New York: Academic, 1968. Translated under the title Gidridy metallov, Moscow: Atomizdat, 1973.

    Google Scholar 

  2. Somenkov, V.A. and Schilshtein, S.Sh., Phase Transition of Hydrogen in Metals, Prog. Mater. Sci., 1980, vol. 24, pp. 267–335.

    Google Scholar 

  3. Skripov, A.V., Phase Transitions and Hydrogen Mobility in Hydrided Alloys and Transition-Metal Compounds, Extended Abstract of Doctoral (Phys.–Math.) Dissertation, Yekaterinburg: Inst. of Metal Physics, Ural Div., Russ. Acad. Sci., 1998.

    Google Scholar 

  4. Kupryazhkin, A.Ya., Shchepetkin, A.A., Zabolotskaya, E.V., et al., Superstoichiometric Zirconium Hydride, Dokl. Akad. Nauk SSSR, 1987, vol. 294, no. 5, pp. 1159–1161.

    Google Scholar 

  5. Kupryazhkin, A.Ya., Pletnev, R.N., Ivanovskii, A.L., et al. Helium-Initiated Structural Phase Transitions in Zirconium Hydride, Dokl. Akad. Nauk SSSR, 1986, vol. 290, no. 5, pp. 1146–1148.

    Google Scholar 

  6. Lichty, L.R., Han, J.W., Ibanez-Meier, R., et al, Low-Temperature Localized Motion of Hydrogen and Electronic Structure Transition of Hexagonal-Closed-Packed Scandium, Phys. Rev. B: Condens. Matter, 1989, vol. 39, no. 4, pp. 2012–2022.

    Google Scholar 

  7. Anderson, I.S., Berk, N.F., Rush, J.J., et al., Rapid Low-Temperature Hopping of Hydrogen in a Pure Metal: The ScHx System, Phys. Rev. Lett., 1990, vol. 65, no. 12, pp. 1439–1442.

    Google Scholar 

  8. Balbach, J.J., Conradi, M.S., Barner, R.G., et al., Nuclear Magnetic Resonance Study of Low-Temperature Localized H(D) Motion in α-ScHx (Dx): Isotope Effects, Phys. Rev. B: Condens. Matter, 1999, vol. 60, no. 2, pp. 966–971.

    Google Scholar 

  9. Naskidashvili, I.A., Low-Temperature Phase Transitions in the Hydrogen Sublattice of Zirconium Hydrides, Fiz. Tverd. Tela (Leningrad), 1976, vol. 18, no. 6, pp. 1502–1507.

    Google Scholar 

  10. Bydlinskaya, I.N., Naskidashvili, I.A., Melik-Shakhnazarov, V.A., and Savin, V.I., A New Low-Temperature Phase Transition of Zirconium Hydride, Fiz. Tverd. Tela (Leningrad), 1980, vol. 22, no. 3, pp. 886–888.

    Google Scholar 

  11. Afanas'ev, M.L., Zeer, E.P., and Kubarev, Yu.G., Magnitnyi rezonans i elektronno-yadernye vzaimodeistviya v kristallakh (Magnetic Resonance and Electron–Nucleus Interactions in Crystals), Novosibirsk: Nauka, 1983.

    Google Scholar 

  12. Wo, J. and Fedin, E.I., Hindered Rotation Barriers in Solids, Fiz. Tverd. Tela (Leningrad), 1962, vol. 4, no. 8, pp. 2233–2237

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pletnev, R.N., Kupryazhkin, A.Y., Dmitriev, A.V. et al. Phase Transition of ZrH2.3 . Inorganic Materials 38, 665–667 (2002). https://doi.org/10.1023/A:1016280106450

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1016280106450

Keywords

Navigation