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Effect of Ultrasonic Processing on Solid-State H+/Cs+ Ion Exchange in Acid Zirconium and Tantalum Phosphates

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Abstract

The effect of ultrasonic processing on solid-state H+/Cs+ ion exchange in the HTa(PO4)2 · 2H2O–CsCl and Zr(HPO4)2 ·H2O–CsCl systems was studied. The rate of ion exchange was found to be substantially higher in the Ta system and to drop with increasing processing time in both systems. In addition, the ultrasonically initiated ion exchange raises the temperatures of subsequent dehydration and solid-state ion exchange in both systems.

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Kislitsyn, M.N., Baranchikov, A.E., Ivanov, V.K. et al. Effect of Ultrasonic Processing on Solid-State H+/Cs+ Ion Exchange in Acid Zirconium and Tantalum Phosphates. Inorganic Materials 38, 714–717 (2002). https://doi.org/10.1023/A:1016248626922

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