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Preparation, Spectral and Thermal Studies of Y(III) and Lanthanide(III) 1-Hydroxy-2-Naphthoates

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Abstract

Complexes of lanthanide(III) (La–Lu) and Y(III) with 1-hydroxy-2-naphthoic acid were obtained as crystalline compounds with a general formula Ln[C10H6(OH)COO]3⋅nH2O:n=6 for La–Tm and Y, n=2 for Yb and n=0 for Lu. IR spectra of the prepared complexes were recorded, and their thermal decomposition in air were investigated. Spectroscopic data suggest that in the coordination of metal-organic ligand only oxygen atoms from the carboxylate group take part. When heated, the complexes decompose to the oxides Ln2O3, CeO2, Pr6O11 and Tb4O7 with intermediate formation of Ln(C11H7O3)(C11H6O3).

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  1. Department of General Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska University, 20-031, Lublin, Poland

    A. Kula

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  1. A. Kula
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Kula, A. Preparation, Spectral and Thermal Studies of Y(III) and Lanthanide(III) 1-Hydroxy-2-Naphthoates. Journal of Thermal Analysis and Calorimetry 68, 957–964 (2002). https://doi.org/10.1023/A:1016198724272

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