Abstract
The kinetics of product accumulation in uncatalyzed oxidation of cyclohexanol at 403 K was studied. Along with the compounds originating from oxidation of cyclohexanol at position 1 (cyclohexanone, hydrogen peroxide, 1-hydroxycyclohexyl hydroperoxide), products formed by oxidation of C-H bonds at positions 2-4 were detected: 2-, 3-, and 4-hydroxycyclohexyl hydroperoxides (cis and trans isomers), 1,2-, 1,3-, and 1,4-dihydroxycyclohexanes (cis and trans isomers), 2- and 4-hydroxycyclohexanones, and 2-cyclohexenone.
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Puchkov, S.V., Buneeva, E.I. & Perkel', A.L. Pathways of Liquid-Phase Oxidation of Cyclohexanol. Russian Journal of Applied Chemistry 75, 248–253 (2002). https://doi.org/10.1023/A:1016160319480
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DOI: https://doi.org/10.1023/A:1016160319480